4-phenyl-1-[2,3,4,6-tetrakis-O-(2,2-dimethylpropanoyl)-D-glucopyranosyl]-1H-[1,2,3]triazole

Base Information

• Chemical Name: 4-phenyl-1-[2,3,4,6-tetrakis-O-(2,2-dimethylpropanoyl)-D-glucopyranosyl]-1H-[1,2,3]triazole
• CAS No.: 1068437-14-8
• Molecular Formula: C₃₄H₄₉N₃O₉
• Molecular Weight: 643.778
• Mol file: 1068437-14-8.mol

Synonyms:4-phenyl-1-[2,3,4,6-tetrakis-O-(2,2-dimethylpropanoyl)-D-glucopyranosyl]-1H-[1,2,3]triazole

Chemical Property of 4-phenyl-1-[2,3,4,6-tetrakis-O-(2,2-dimethylpropanoyl)-D-glucopyranosyl]-1H-[1,2,3]triazole

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of 4-phenyl-1-[2,3,4,6-tetrakis-O-(2,2-dimethylpropanoyl)-D-glucopyranosyl]-1H-[1,2,3]triazole

There total 4 articles about 4-phenyl-1-[2,3,4,6-tetrakis-O-(2,2-dimethylpropanoyl)-D-glucopyranosyl]-1H-[1,2,3]triazole which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 92.3%

1-azido-2,3,4,6-tetra-O-pivaloyl-β-D-glucopyranose + phenylacetylene (536-74-3) → 4-phenyl-1-[2,3,4,6-tetrakis-O-(2,2-dimethylpropanoyl)-D-glucopyranosyl]-1H-[1,2,3]triazole (1068437-14-8)

Guidance literature:

With copper(II) sulfate; sodium L-ascorbate; In water; tert-butyl alcohol; for 24h;

DOI:10.1002/hlca.201000093

Reference yield: 92.0%

phenylacetylene (536-74-3) + 1,2,3,4,6-penta-O-pivaloyl-D-glucopyranosylazide → 4-phenyl-1-[2,3,4,6-tetrakis-O-(2,2-dimethylpropanoyl)-D-glucopyranosyl]-1H-[1,2,3]triazole (1068437-14-8)

Guidance literature:

With copper(II) sulfate; sodium L-ascorbate; In water; tert-butyl alcohol; for 24h;

DOI:10.1080/07328303.2010.487231

Reference yield: 89.0%

phenylacetylene (536-74-3) + 2,3,4,6-tetra-O-pivaloyl-β-D-glucopyranosyl azide (131603-21-9) → 4-phenyl-1-[2,3,4,6-tetrakis-O-(2,2-dimethylpropanoyl)-D-glucopyranosyl]-1H-[1,2,3]triazole (1068437-14-8)

Guidance literature:

With cellulose supported copper⁽⁰⁾; In water; at 60 ℃; for 12h;

DOI:10.1016/j.catcom.2016.02.015

upstream raw materials:

phenylacetylene

1,2,3,4,6-penta-O-pivaloyl-D-glucopyranoside

2,3,4,6-tetra-O-pivaloyl-β-D-glucopyranosyl azide

Downstream raw materials:

(2R,3S,4S,5R,6R)-2-(hydroxymethyl)-6-(4-phenyltriazol-1-yl)tetrahydropyran-3,4,5-triol