nickel(II) 2,3-bis(isopropylethynyl)-5,10,15,20-tetraphenylporphyrin

Base Information

• Chemical Name: nickel(II) 2,3-bis(isopropylethynyl)-5,10,15,20-tetraphenylporphyrin
• CAS No.: 1351565-30-4
• Molecular Formula: C₅₄H₄₀N₄Ni
• Molecular Weight: 803.628
• Mol file: 1351565-30-4.mol

Synonyms:nickel(II) 2,3-bis(isopropylethynyl)-5,10,15,20-tetraphenylporphyrin

Chemical Property of nickel(II) 2,3-bis(isopropylethynyl)-5,10,15,20-tetraphenylporphyrin

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of nickel(II) 2,3-bis(isopropylethynyl)-5,10,15,20-tetraphenylporphyrin

There total 1 articles about nickel(II) 2,3-bis(isopropylethynyl)-5,10,15,20-tetraphenylporphyrin which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 80.0%

2,3-dibromo-5,10,15,20-tetraphenylporphyrinatonickel(II) (253134-81-5) + 3-methyl-1-(trimethylstannyl)but-1-yne (22015-17-4) → nickel(II) 2,3-bis(isopropylethynyl)-5,10,15,20-tetraphenylporphyrin (1351565-30-4)

Guidance literature:

With tetrakis(triphenylphosphine) palladium⁽⁰⁾; In tetrahydrofuran; at 70 - 80 ℃; for 5h; Inert atmosphere;

DOI:10.1016/j.jorganchem.2011.07.008

Reference yield: 10.0%

nickel(II) 2,3-bis(isopropylethynyl)-5,10,15,20-tetraphenylporphyrin (1351565-30-4) → C54H42Cl2N4Ni (1351565-51-9) + C54H41ClN4Ni (1351565-53-1) + Ni(C20H6N4(C6H5)3(C6H4C4H(CH(CH3)2)2)) (1351565-43-9) + Ni(C20H6N4(C6H5)2(C6H4)2C4(CH(CH3)2)2) (1351565-49-5)

Guidance literature:

With platinum(II) chloride; In toluene; at 115 ℃; for 24h; Inert atmosphere;

DOI:10.1016/j.jorganchem.2011.07.008

Reference yield: 10.0%

nickel(II) 2,3-bis(isopropylethynyl)-5,10,15,20-tetraphenylporphyrin (1351565-30-4) → Ni(C20H6N4(C6H5)3(C6H4C4H(CH(CH3)2)2)) (1351565-43-9) + Ni(C20H6N4(C6H5)2(C6H4)2C4(CH(CH3)2)2) (1351565-49-5) + C54H41ClN4Ni + C54H42Cl2N4Ni

Guidance literature:

platinum(II) chloride; In toluene; mixt. of Ni complex and PtCl2 in toluene heated in pressure tube at 115°C for 24 h; react. mixt. cooled to 25°C; diluted with CH2Cl2; solvent evapd. under reduced pressure, crude product loaded on alumina column; green fraction collected, eluted with CH2Cl2/hexane;

DOI:10.1016/j.jorganchem.2011.07.008

upstream raw materials:

2,3-dibromo-5,10,15,20-tetraphenylporphyrinatonickel(II)

3-methyl-1-(trimethylstannyl)but-1-yne

Downstream raw materials:

C₅₄H₄₂Cl₂N₄Ni

C₅₄H₄₁ClN₄Ni

Ni(C₂₀H₆N₄(C₆H₅)3(C₆H₄C₄H(CH(CH₃)2)2))

Ni(C₂₀H₆N₄(C₆H₅)2(C₆H₄)2C₄(CH(CH₃)2)2)