tri(tert-butyl) [1S,1(4R,5R),3S,4S,5R,6R,7R]-4,6,7-trihydroxy-1-(4-hydroxy-5-methyl-6-phenylhexyl)-2,8-dioxabicyclo[3.2.1]octane-3,4,5-tricarboxylate

Base Information

Chemical Name:tri(tert-butyl) [1S,1(4R,5R),3S,4S,5R,6R,7R]-4,6,7-trihydroxy-1-(4-hydroxy-5-methyl-6-phenylhexyl)-2,8-dioxabicyclo[3.2.1]octane-3,4,5-tricarboxylate
CAS No.:191935-36-1
Molecular Formula:C₃₄H₅₂O₁₂
Molecular Weight:652.78
Hs Code.:

Synonyms:tri(tert-butyl) [1S,1(4R,5R),3S,4S,5R,6R,7R]-4,6,7-trihydroxy-1-(4-hydroxy-5-methyl-6-phenylhexyl)-2,8-dioxabicyclo[3.2.1]octane-3,4,5-tricarboxylate

Suppliers and Price of tri(tert-butyl) [1S,1(4R,5R),3S,4S,5R,6R,7R]-4,6,7-trihydroxy-1-(4-hydroxy-5-methyl-6-phenylhexyl)-2,8-dioxabicyclo[3.2.1]octane-3,4,5-tricarboxylate

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 0 raw suppliers

Chemical Property of tri(tert-butyl) [1S,1(4R,5R),3S,4S,5R,6R,7R]-4,6,7-trihydroxy-1-(4-hydroxy-5-methyl-6-phenylhexyl)-2,8-dioxabicyclo[3.2.1]octane-3,4,5-tricarboxylate

Chemical Property:

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:

Useful:

Technology Process of tri(tert-butyl) [1S,1(4R,5R),3S,4S,5R,6R,7R]-4,6,7-trihydroxy-1-(4-hydroxy-5-methyl-6-phenylhexyl)-2,8-dioxabicyclo[3.2.1]octane-3,4,5-tricarboxylate

There total 34 articles about tri(tert-butyl) [1S,1(4R,5R),3S,4S,5R,6R,7R]-4,6,7-trihydroxy-1-(4-hydroxy-5-methyl-6-phenylhexyl)-2,8-dioxabicyclo[3.2.1]octane-3,4,5-tricarboxylate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 90.0%

: 191935-35-0
tri(tert-butyl) [1S,1(4R,5R),3S,4S,5R,6R,7R]-1-(4-benzyloxy-5-methyl-6-phenylhexyl)-4,6,7-trihydroxy-2,8-dioxabicyclo[3.2.1]octane-3,4,5-tricarboxylate

: 191935-36-1
tri(tert-butyl) [1S,1(4R,5R),3S,4S,5R,6R,7R]-4,6,7-trihydroxy-1-(4-hydroxy-5-methyl-6-phenylhexyl)-2,8-dioxabicyclo[3.2.1]octane-3,4,5-tricarboxylate

Guidance literature:: With hydrogen; palladium on activated charcoal; In methanol; for 17h; under 760 Torr;
DOI:10.1016/j.tet.2005.09.030

Reference yield:

: 71432-55-8
2-tert-butyl-1,3-diisopropylisourea

: 191935-36-1
tri(tert-butyl) [1S,1(4R,5R),3S,4S,5R,6R,7R]-4,6,7-trihydroxy-1-(4-hydroxy-5-methyl-6-phenylhexyl)-2,8-dioxabicyclo[3.2.1]octane-3,4,5-tricarboxylate

Guidance literature:: Multi-step reaction with 2 steps

1.1: KOH / H₂O; dioxane / 24 h / 100 °C

1.2: 40 percent / CH₂Cl₂ / 24 h / 20 °C

2.1: 90 percent / hydrogen / palladium on carbon / methanol / 17 h / 760 Torr

With potassium hydroxide; hydrogen; palladium on activated charcoal; In 1,4-dioxane; methanol; water;
DOI:10.1016/j.tet.2005.09.030

Reference yield:

: (1S,3S,4S,5R,6R,7R)-1-((4R,5R)-4-Benzyloxy-5-methyl-6-phenyl-hexyl)-4,6,7-trihydroxy-2,8-dioxa-bicyclo[3.2.1]octane-3,4,5-tricarboxylic acid

: 191935-36-1
tri(tert-butyl) [1S,1(4R,5R),3S,4S,5R,6R,7R]-4,6,7-trihydroxy-1-(4-hydroxy-5-methyl-6-phenylhexyl)-2,8-dioxabicyclo[3.2.1]octane-3,4,5-tricarboxylate

Guidance literature:: Multi-step reaction with 2 steps

1: CH₂Cl₂ / 24 h

2: 86 percent / H₂ / 10percent Pd/C / methanol / 34 h

With hydrogen; palladium on activated charcoal; In methanol; dichloromethane;
DOI:10.1055/s-1997-6154