(Z,Z)-4-{5-[2-[(benzyloxycarbonyl)amino]-2-(methoxycarbonyl)ethenyl]-2-methoxyphenoxy}-1-{2-[(tert-butyloxycarbonyl)amino]-2-[[2-(trimethylsilyl)ethoxy]carbonyl]ethenyl}benzene

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Chemical Name:(Z,Z)-4-{5-[2-[(benzyloxycarbonyl)amino]-2-(methoxycarbonyl)ethenyl]-2-methoxyphenoxy}-1-{2-[(tert-butyloxycarbonyl)amino]-2-[[2-(trimethylsilyl)ethoxy]carbonyl]ethenyl}benzene
CAS No.:247167-35-7
Molecular Formula:C₃₈H₄₆N₂O₁₀Si
Molecular Weight:718.876
Hs Code.:

(Z,Z)-4-{5-[2-[(benzyloxycarbonyl)amino]-2-(methoxycarbonyl)ethenyl]-2-methoxyphenoxy}-1-{2-[(tert-butyloxycarbonyl)amino]-2-[[2-(trimethylsilyl)ethoxy]carbonyl]ethenyl}benzene

Synonyms:(Z,Z)-4-{5-[2-[(benzyloxycarbonyl)amino]-2-(methoxycarbonyl)ethenyl]-2-methoxyphenoxy}-1-{2-[(tert-butyloxycarbonyl)amino]-2-[[2-(trimethylsilyl)ethoxy]carbonyl]ethenyl}benzene

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Chemical Property of (Z,Z)-4-{5-[2-[(benzyloxycarbonyl)amino]-2-(methoxycarbonyl)ethenyl]-2-methoxyphenoxy}-1-{2-[(tert-butyloxycarbonyl)amino]-2-[[2-(trimethylsilyl)ethoxy]carbonyl]ethenyl}benzene

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Technology Process of (Z,Z)-4-{5-[2-[(benzyloxycarbonyl)amino]-2-(methoxycarbonyl)ethenyl]-2-methoxyphenoxy}-1-{2-[(tert-butyloxycarbonyl)amino]-2-[[2-(trimethylsilyl)ethoxy]carbonyl]ethenyl}benzene

There total 9 articles about (Z,Z)-4-{5-[2-[(benzyloxycarbonyl)amino]-2-(methoxycarbonyl)ethenyl]-2-methoxyphenoxy}-1-{2-[(tert-butyloxycarbonyl)amino]-2-[[2-(trimethylsilyl)ethoxy]carbonyl]ethenyl}benzene which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 85.0%

: 134038-88-3
2-(trimethylsilyl)ethyl α-(dimethoxyphosphoryl)-N-(benzyloxycarbonyl)glycinate

: 247167-34-6
(Z)-4-(5-formyl-2-methoxyphenoxy)-1-{2-[(tert-butyloxycarbonyl)amino]-2-(methoxycarbonyl)ethenyl}benzene

: 247167-35-7
(Z,Z)-4-{5-[2-[(benzyloxycarbonyl)amino]-2-(methoxycarbonyl)ethenyl]-2-methoxyphenoxy}-1-{2-[(tert-butyloxycarbonyl)amino]-2-[[2-(trimethylsilyl)ethoxy]carbonyl]ethenyl}benzene

Guidance literature:: With 1,8-diazabicyclo[5.4.0]undec-7-ene; In dichloromethane; at 20 ℃; for 2h;
DOI:10.1016/S0040-4020(99)00576-1

Reference yield:

: 624-38-4,1032416-46-8
para-diiodobenzene

: 247167-35-7
(Z,Z)-4-{5-[2-[(benzyloxycarbonyl)amino]-2-(methoxycarbonyl)ethenyl]-2-methoxyphenoxy}-1-{2-[(tert-butyloxycarbonyl)amino]-2-[[2-(trimethylsilyl)ethoxy]carbonyl]ethenyl}benzene

Guidance literature:: Multi-step reaction with 3 steps

1: 27 percent / potassium carbonate; copper(II) oxide / pyridine / 24 h / Heating

2: 97 percent / tetrabutylammonium chloride; NaHCO₃ / palladium(II) diacetate / dimethylformamide / 20 h / 85 °C

3: 85 percent / DBU / CH₂Cl₂ / 2 h / 20 °C

With tetrabutyl-ammonium chloride; sodium hydrogencarbonate; potassium carbonate; 1,8-diazabicyclo[5.4.0]undec-7-ene; copper(II) oxide; palladium diacetate; In pyridine; dichloromethane; N,N-dimethyl-formamide; 1: Ullmann coupling reaction / 2: Heck coupling / 3: Horner-Wadsworth-Emmons olefination;
DOI:10.1016/S0040-4020(99)00576-1

Reference yield:

: 589-87-7
1,4-bromoiodobenzene

: 247167-35-7
(Z,Z)-4-{5-[2-[(benzyloxycarbonyl)amino]-2-(methoxycarbonyl)ethenyl]-2-methoxyphenoxy}-1-{2-[(tert-butyloxycarbonyl)amino]-2-[[2-(trimethylsilyl)ethoxy]carbonyl]ethenyl}benzene

Guidance literature:: Multi-step reaction with 4 steps

1: potassium carbonate; copper(II) oxide / pyridine / Heating

2: 27 percent / potassium carbonate; copper(II) oxide / pyridine / 24 h / Heating

3: 97 percent / tetrabutylammonium chloride; NaHCO₃ / palladium(II) diacetate / dimethylformamide / 20 h / 85 °C

4: 85 percent / DBU / CH₂Cl₂ / 2 h / 20 °C

With tetrabutyl-ammonium chloride; sodium hydrogencarbonate; potassium carbonate; 1,8-diazabicyclo[5.4.0]undec-7-ene; copper(II) oxide; palladium diacetate; In pyridine; dichloromethane; N,N-dimethyl-formamide; 1: Ullmann coupling reaction / 2: Ullmann coupling reaction / 3: Heck coupling / 4: Horner-Wadsworth-Emmons olefination;
DOI:10.1016/S0040-4020(99)00576-1