bis[4-(3′,5′-di-tert-butylphenyl)-7-methoxy-2-methylindenyl]dimethylsilane

Base Information

Chemical Name:bis[4-(3′,5′-di-tert-butylphenyl)-7-methoxy-2-methylindenyl]dimethylsilane
CAS No.:1379658-33-9
Molecular Formula:C₅₂H₆₈O₂Si
Molecular Weight:753.196
Hs Code.:

Synonyms:bis[4-(3′,5′-di-tert-butylphenyl)-7-methoxy-2-methylindenyl]dimethylsilane

Suppliers and Price of bis[4-(3′,5′-di-tert-butylphenyl)-7-methoxy-2-methylindenyl]dimethylsilane

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 0 raw suppliers

Chemical Property of bis[4-(3′,5′-di-tert-butylphenyl)-7-methoxy-2-methylindenyl]dimethylsilane

Chemical Property:

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:

Useful:

Technology Process of bis[4-(3′,5′-di-tert-butylphenyl)-7-methoxy-2-methylindenyl]dimethylsilane

There total 8 articles about bis[4-(3′,5′-di-tert-butylphenyl)-7-methoxy-2-methylindenyl]dimethylsilane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 36.0%

: 1379658-32-8
2-methyl-4-methoxy-7-(3,5-di-tert-butylphenyl)-1H-indene

: 75-78-5,30107-43-8
dimethylsilicon dichloride

: 1379658-33-9
bis[4-(3′,5′-di-tert-butylphenyl)-7-methoxy-2-methylindenyl]dimethylsilane

Guidance literature:: With n-butyllithium; In 1,4-dioxane; hexane; toluene; at -20 - 60 ℃;
DOI:10.1002/chem.201103547

Reference yield:

: 1393604-93-7
4-(3',5'-di-tert-butylphenyl)-7-methoxy-2-methylindene

: 75-78-5,30107-43-8
dimethylsilicon dichloride

: 1379658-33-9
bis[4-(3′,5′-di-tert-butylphenyl)-7-methoxy-2-methylindenyl]dimethylsilane

Guidance literature:: 4-(3',5'-di-tert-butylphenyl)-7-methoxy-2-methylindene; With n-butyllithium; copper(l) cyanide; In tetrahydrofuran; hexane; toluene; at -20 ℃; for 4h;

dimethylsilicon dichloride; In tetrahydrofuran; hexane; toluene; at 20 ℃; for 24h;

Reference yield:

: 22385-77-9
1-bromo-3,5-di-tert-butylbenzene

: 1379658-33-9
bis[4-(3′,5′-di-tert-butylphenyl)-7-methoxy-2-methylindenyl]dimethylsilane

Guidance literature:: Multi-step reaction with 3 steps

1: magnesium / tetrahydrofuran; diethyl ether / -60 - 20 °C / Reflux

2: tetrakis(triphenylphosphine) palladium⁽⁰⁾; sodium carbonate / ethanol; toluene / 72 h / Reflux

3: n-butyllithium / 1,4-dioxane; hexane; toluene / -20 - 60 °C

With tetrakis(triphenylphosphine) palladium⁽⁰⁾; n-butyllithium; sodium carbonate; magnesium; In tetrahydrofuran; 1,4-dioxane; diethyl ether; ethanol; hexane; toluene;
DOI:10.1002/chem.201103547