1-O-triisopropylsilyl-2-deoxy-2,2-difluoro-5-O-benzoyl-D-arabinofuranose

Base Information

Chemical Name:1-O-triisopropylsilyl-2-deoxy-2,2-difluoro-5-O-benzoyl-D-arabinofuranose
CAS No.:1151529-01-9
Molecular Formula:C₂₁H₃₂F₂O₅Si
Molecular Weight:430.564
Hs Code.:

Synonyms:1-O-triisopropylsilyl-2-deoxy-2,2-difluoro-5-O-benzoyl-D-arabinofuranose

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Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of 1-O-triisopropylsilyl-2-deoxy-2,2-difluoro-5-O-benzoyl-D-arabinofuranose

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Technology Process of 1-O-triisopropylsilyl-2-deoxy-2,2-difluoro-5-O-benzoyl-D-arabinofuranose

There total 3 articles about 1-O-triisopropylsilyl-2-deoxy-2,2-difluoro-5-O-benzoyl-D-arabinofuranose which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 56.0%

: 1151529-00-8
1-O-triisopropylsilyl-2-deoxy-2,2-difluoro-3,5-di-O-benzoyl-D-arabinofuranose

: 1151529-02-0
1-O-triisopropylsilyl-2-deoxy-2,2-difluoro-D-arabinofuranose

: 1151529-01-9
1-O-triisopropylsilyl-2-deoxy-2,2-difluoro-5-O-benzoyl-D-arabinofuranose

Guidance literature:: With methanol; water; triethylamine; at 23 ℃; for 17h;

Reference yield:

: 80522-42-5
triisopropylsilyl trifluoromethanesulfonate

: 1173824-58-2,143157-25-9,143157-22-6
(2R,3R)-2-((benzoyloxy)methyl)-4,4-difluoro-5-hydroxyoxolan-3-yl benzoate

: 1151529-01-9
1-O-triisopropylsilyl-2-deoxy-2,2-difluoro-5-O-benzoyl-D-arabinofuranose

: 1430067-47-2
1-O-triisopropylsilyl-2-deoxy-2,2-difluoro-3,5-di-O-benzoyl-α-D-arabinofuranose

: 1430067-48-3
1-O-triisopropylsilyl-2-deoxy-2,2-difluoro-3,5-di-O-benzoyl-β-D-arabinofuranose

: 1430067-49-4
1-O-triisopropylsilyl-2-deoxy-2,2-difluoro-3-O-benzoyl-D-arabinofuranose

Guidance literature:: With 2,6-dimethylpyridine; In dichloromethane; at 0 ℃;
DOI:10.1016/j.bmcl.2013.02.117

Reference yield:

: 122111-01-7,122111-02-8
2-deoxy-2,2-difluoro-D-erythro-pentonic acid γ-lactone 3,5-dibenzoate

: 1151529-01-9
1-O-triisopropylsilyl-2-deoxy-2,2-difluoro-5-O-benzoyl-D-arabinofuranose

: 1430067-47-2
1-O-triisopropylsilyl-2-deoxy-2,2-difluoro-3,5-di-O-benzoyl-α-D-arabinofuranose

: 1430067-48-3
1-O-triisopropylsilyl-2-deoxy-2,2-difluoro-3,5-di-O-benzoyl-β-D-arabinofuranose

: 1430067-49-4
1-O-triisopropylsilyl-2-deoxy-2,2-difluoro-3-O-benzoyl-D-arabinofuranose

Guidance literature:: Multi-step reaction with 2 steps

1: lithium tri-t-butoxyaluminum hydride / tetrahydrofuran; diethyl ether / -78 °C

2: 2,6-dimethylpyridine / dichloromethane / 0 °C

With 2,6-dimethylpyridine; lithium tri-t-butoxyaluminum hydride; In tetrahydrofuran; diethyl ether; dichloromethane;
DOI:10.1016/j.bmcl.2013.02.117