[6,8,8,8-(CO)4-6-H-6-PPh₃-10-OPPh₃-closo-6,8,1-IrFeCB₇H₇]

Base Information

• Chemical Name: [6,8,8,8-(CO)4-6-H-6-PPh₃-10-OPPh₃-closo-6,8,1-IrFeCB₇H₇]
• CAS No.: 920968-60-1
• Molecular Formula: C₄₁H₃₈B₇FeIrO₅P₂
• Molecular Weight: 996.441
• Mol file: 920968-60-1.mol

Synonyms:[6,8,8,8-(CO)4-6-H-6-PPh₃-10-OPPh₃-closo-6,8,1-IrFeCB₇H₇]

Chemical Property of [6,8,8,8-(CO)4-6-H-6-PPh₃-10-OPPh₃-closo-6,8,1-IrFeCB₇H₇]

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of [6,8,8,8-(CO)4-6-H-6-PPh₃-10-OPPh₃-closo-6,8,1-IrFeCB₇H₇]

There total 1 articles about [6,8,8,8-(CO)4-6-H-6-PPh₃-10-OPPh₃-closo-6,8,1-IrFeCB₇H₇] which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 44.0%

bis(triphenylphosphine)carbonyliridium(I) chloride (59246-46-7,14871-41-1,15318-31-7) + [N(PPh3)2][7,7,7-(CO)3-closo-7,1-FeCB7H8] → [6,8,8,8-(CO)4-6-H-6-PPh3-10-OPPh3-closo-6,8,1-IrFeCB7H7] (920968-60-1) + [7,7,9,9,9-(CO)5-7-PPh3-closo-7,9,1-IrFeCB6H7] + [6,7,9-(Ir(CO)(PPh3)2)-7,9-(μ-H)2-7,9,9-(CO)3-7-PPh3-closo-7,9,1-IrFeCB6H6]

Guidance literature:

With TlPF₆; In dichloromethane; byproducts: TlCl; under N2; Fe complex, Ir complex and TlPF6 in CH2Cl2 stirred for 48 h; solvent removed in vac.; extd. with CH2Cl2; extract filtered (Celite); sepd. by column chromy. (silica gel, CH2Cl2-petroleum ether 1:1); solventremoved in vac.; elem. anal.;

DOI:10.1021/ja065042n

upstream raw materials:

bis(triphenylphosphine)carbonyliridium(I) chloride