1-[benzyl(butyl-4'-O-dodecyl)]-3,4,6-tri-O-benzyl-2,5-anhydro-D-glucityl phosphonate

Base Information

Chemical Name:1-[benzyl(butyl-4'-O-dodecyl)]-3,4,6-tri-O-benzyl-2,5-anhydro-D-glucityl phosphonate
CAS No.:479404-74-5
Molecular Formula:C₅₀H₆₉O₈P
Molecular Weight:829.067
Hs Code.:

Synonyms:1-[benzyl(butyl-4'-O-dodecyl)]-3,4,6-tri-O-benzyl-2,5-anhydro-D-glucityl phosphonate

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Chemical Property of 1-[benzyl(butyl-4'-O-dodecyl)]-3,4,6-tri-O-benzyl-2,5-anhydro-D-glucityl phosphonate

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Technology Process of 1-[benzyl(butyl-4'-O-dodecyl)]-3,4,6-tri-O-benzyl-2,5-anhydro-D-glucityl phosphonate

There total 8 articles about 1-[benzyl(butyl-4'-O-dodecyl)]-3,4,6-tri-O-benzyl-2,5-anhydro-D-glucityl phosphonate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 86.0%

: 1-[benzyl(2'-butenyl-4'-O-dodecyl)]-3,4,6-tri-O-benzyl-2,5-anhydro-D-glucityl phosphonate

: 479404-74-5
1-[benzyl(butyl-4'-O-dodecyl)]-3,4,6-tri-O-benzyl-2,5-anhydro-D-glucityl phosphonate

Guidance literature:: With potassium diazodicarboxylate; acetic acid; In methanol; at 40 ℃;
DOI:10.1021/jo026247r

Reference yield:

: 4292-19-7
1-Iodododecane

: 479404-74-5
1-[benzyl(butyl-4'-O-dodecyl)]-3,4,6-tri-O-benzyl-2,5-anhydro-D-glucityl phosphonate

Guidance literature:: Multi-step reaction with 3 steps

1.1: NaH / dimethylformamide / 0.17 h / 20 °C

1.2: 99 percent / dimethylformamide / 1 h / 20 °C

2.1: (PCy₃)2RuCl₂(=CHPh) / CH₂Cl₂ / 3 h / Heating

3.1: 86 percent / dipotassium azodicarboxylate; glacial AcOH / methanol / 40 °C

With Grubbs catalyst first generation; potassium diazodicarboxylate; sodium hydride; acetic acid; In methanol; dichloromethane; N,N-dimethyl-formamide;
DOI:10.1021/jo026247r

Reference yield:

: 479404-45-0
cis-2-butenyl-1,4-didodecyl ether

: 479404-74-5
1-[benzyl(butyl-4'-O-dodecyl)]-3,4,6-tri-O-benzyl-2,5-anhydro-D-glucityl phosphonate

Guidance literature:: Multi-step reaction with 2 steps

1: (PCy₃)2RuCl₂(=CHPh) / CH₂Cl₂ / 3 h / Heating

2: 86 percent / dipotassium azodicarboxylate; glacial AcOH / methanol / 40 °C

With Grubbs catalyst first generation; potassium diazodicarboxylate; acetic acid; In methanol; dichloromethane;
DOI:10.1021/jo026247r