1-hydroxy-1-(2',6'-dithiacyclohexyl)-3-(3'-t-butyldiphenylsilyloxypropyl)cyclopentane

Base Information

Chemical Name:1-hydroxy-1-(2',6'-dithiacyclohexyl)-3-(3'-t-butyldiphenylsilyloxypropyl)cyclopentane
CAS No.:358351-36-7
Molecular Formula:C₂₈H₄₀O₂S₂Si
Molecular Weight:500.842
Hs Code.:

Synonyms:1-hydroxy-1-(2',6'-dithiacyclohexyl)-3-(3'-t-butyldiphenylsilyloxypropyl)cyclopentane

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Chemical Property of 1-hydroxy-1-(2',6'-dithiacyclohexyl)-3-(3'-t-butyldiphenylsilyloxypropyl)cyclopentane

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Technology Process of 1-hydroxy-1-(2',6'-dithiacyclohexyl)-3-(3'-t-butyldiphenylsilyloxypropyl)cyclopentane

There total 7 articles about 1-hydroxy-1-(2',6'-dithiacyclohexyl)-3-(3'-t-butyldiphenylsilyloxypropyl)cyclopentane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 80.0%

: 505-23-7
1,3 dithiane

: 358351-43-6
3-(3'-t-butyldiphenylsilyloxypropyl)cyclopentan-1-one

: 358351-36-7
1-hydroxy-1-(2',6'-dithiacyclohexyl)-3-(3'-t-butyldiphenylsilyloxypropyl)cyclopentane

Guidance literature:: With n-butyllithium; In tetrahydrofuran; hexane; at 0 - 20 ℃; for 1h;
DOI:10.1016/S0040-4020(01)00358-1

Reference yield:

: 930-30-3
cyclopent-2-enone

: 358351-36-7
1-hydroxy-1-(2',6'-dithiacyclohexyl)-3-(3'-t-butyldiphenylsilyloxypropyl)cyclopentane

Guidance literature:: Multi-step reaction with 6 steps

1.1: 80 percent / CuBr/Me₂S; LiCl; TMSCl / tetrahydrofuran / 0.08 h / -78 °C

2.1: montmorillonite K-10 clay / pentane / 6 h / 20 °C

3.1: borane dimethylsulfide; 2-methyl-2-butene / tetrahydrofuran / 2 h / 20 °C

3.2: 30 percent H₂O₂; 3M NaOH / tetrahydrofuran / 16 h / 20 °C

4.1: 4.12 g / montmorillonite K-10 clay / acetone; H₂O / 12 h / 20 °C

5.1: 80 percent / imidazole / dimethylformamide / 12 h / 20 °C

6.1: 80 percent / n-BuLi / tetrahydrofuran; hexane / 1 h / 0 - 20 °C

With 1H-imidazole; n-butyllithium; chloro-trimethyl-silane; 2-methyl-but-2-ene; dimethylsulfide; dimethylsulfide borane complex; Montmorillonite K-10 clay; lithium chloride; copper(I) bromide; In tetrahydrofuran; hexane; water; N,N-dimethyl-formamide; acetone; pentane;
DOI:10.1016/S0040-4020(01)00358-1

Reference yield:

: 73057-67-7
3-(2'-propenyl)cyclopentanone

: 358351-36-7
1-hydroxy-1-(2',6'-dithiacyclohexyl)-3-(3'-t-butyldiphenylsilyloxypropyl)cyclopentane

Guidance literature:: Multi-step reaction with 5 steps

1.1: montmorillonite K-10 clay / pentane / 6 h / 20 °C

2.1: borane dimethylsulfide; 2-methyl-2-butene / tetrahydrofuran / 2 h / 20 °C

2.2: 30 percent H₂O₂; 3M NaOH / tetrahydrofuran / 16 h / 20 °C

3.1: 4.12 g / montmorillonite K-10 clay / acetone; H₂O / 12 h / 20 °C

4.1: 80 percent / imidazole / dimethylformamide / 12 h / 20 °C

5.1: 80 percent / n-BuLi / tetrahydrofuran; hexane / 1 h / 0 - 20 °C

With 1H-imidazole; n-butyllithium; 2-methyl-but-2-ene; dimethylsulfide borane complex; Montmorillonite K-10 clay; In tetrahydrofuran; hexane; water; N,N-dimethyl-formamide; acetone; pentane;
DOI:10.1016/S0040-4020(01)00358-1