(S)-di-O-benzylcurvularin

Base Information

Chemical Name:(S)-di-O-benzylcurvularin
CAS No.:65732-22-1
Molecular Formula:C₃₀H₃₂O₅
Molecular Weight:472.581
Hs Code.:

Synonyms:(S)-di-O-benzylcurvularin

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Chemical Property of (S)-di-O-benzylcurvularin

Chemical Property:

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Technology Process of (S)-di-O-benzylcurvularin

There total 7 articles about (S)-di-O-benzylcurvularin which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 30.0%

: 1215006-49-7
3,5-dibenzyloxy-2-trimethylsilylphenyl trifluoromethanesulfonate

: 1217889-23-0
C₁₀H₁₆O₃

: 65732-22-1
(S)-di-O-benzylcurvularin

Guidance literature:: With cesium fluoride; In acetonitrile; at 40 ℃; Inert atmosphere;
DOI:10.1021/ol100335y

Reference yield:

: tert-butyl (7S,2E,4E)-7-hydroxyocta-2,4-dienoate

: 65732-22-1
(S)-di-O-benzylcurvularin

Guidance literature:: Multi-step reaction with 5 steps

1: hydrogen; palladium on activated charcoal / dichloromethane / 20 °C / 760.05 Torr / Inert atmosphere

2: pyridine; 2-Bromoacetyl bromide / dichloromethane / 0 - 20 °C / Inert atmosphere

3: palladium diacetate; potassium phosphate; tris-(o-tolyl)phosphine / tetrahydrofuran; water / 24 h / Glovebox

4: 2,6-dimethylpyridine; trimethylsilyl trifluoromethanesulfonate / 0 - 20 °C / Inert atmosphere

5: trifluoroacetic acid; trifluoroacetic anhydride / 6 h / 20 °C

With pyridine; 2,6-dimethylpyridine; potassium phosphate; trimethylsilyl trifluoromethanesulfonate; palladium on activated charcoal; hydrogen; palladium diacetate; 2-Bromoacetyl bromide; tris-(o-tolyl)phosphine; trifluoroacetic acid; trifluoroacetic anhydride; In tetrahydrofuran; dichloromethane; water;
DOI:10.1002/ejoc.201500287

Reference yield:

: 120982-13-0
tert-butyl (7S)-7-hydroxyoctanoate

: 65732-22-1
(S)-di-O-benzylcurvularin

Guidance literature:: Multi-step reaction with 4 steps

1: pyridine; 2-Bromoacetyl bromide / dichloromethane / 0 - 20 °C / Inert atmosphere

2: palladium diacetate; potassium phosphate; tris-(o-tolyl)phosphine / tetrahydrofuran; water / 24 h / Glovebox

3: 2,6-dimethylpyridine; trimethylsilyl trifluoromethanesulfonate / 0 - 20 °C / Inert atmosphere

4: trifluoroacetic acid; trifluoroacetic anhydride / 6 h / 20 °C

With pyridine; 2,6-dimethylpyridine; potassium phosphate; trimethylsilyl trifluoromethanesulfonate; palladium diacetate; 2-Bromoacetyl bromide; tris-(o-tolyl)phosphine; trifluoroacetic acid; trifluoroacetic anhydride; In tetrahydrofuran; dichloromethane; water;
DOI:10.1002/ejoc.201500287