Technology Process of (C5(CH3)5)Re(NO)(P(C6H5)3)(C(O)CH2C6H5)
There total 1 articles about (C5(CH3)5)Re(NO)(P(C6H5)3)(C(O)CH2C6H5) which
guide to synthetic route it.
The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:
synthetic route:
- Guidance literature:
-
In
tetrahydrofuran; toluene;
under dry N2; to stirred soln. of Re complex in toluene is added at room temp. PhCH2MgCl in THF, stirred for 45 min; solvents removed in vac., extd. (acetone), extract filtered through a plug of SiO2, concd. in vac., addn. of hexane, kept for 16 h at -24°C, ppt. filtered, dried in vac.; elem. anal.;
DOI:10.1021/ja00266a012
- Guidance literature:
-
With
n-butyllithium; methyl iodide;
In
tetrahydrofuran; hexane;
under dry N2; soln. of Re complex in THF is cooled to -78°C, addn. of n-BuLi in hexane, after 45 min addn. of CH3I, stirred for 25 min at -78°C; solvents are removed under oil pump vac. at 0°C, chromd. (SiO2, CH2Cl2), recrystd. (acetone/pentane); elem. anal.;
DOI:10.1021/ja00266a012
