2,3,4,8b-Tetrahydro-1aH-1-oxa-benzo[a]cyclopropa[c]cycloheptene

Base Information

Chemical Name:2,3,4,8b-Tetrahydro-1aH-1-oxa-benzo[a]cyclopropa[c]cycloheptene
CAS No.:4443-71-4
Molecular Formula:C₁₁H₁₂O
Molecular Weight:160.216
Hs Code.:2932999099
DSSTox Substance ID:DTXSID60447573
Nikkaji Number:J645.260D
Mol file:4443-71-4.mol

Synonyms:4443-71-4;2,3,4,8b-Tetrahydro-1aH-1-oxa-benzo[a]cyclopropa[c]cycloheptene;3-oxatricyclo[6.4.0.02,4]dodeca-1(12),8,10-triene;SCHEMBL9492857;DTXSID60447573;AKOS000140702;6,7,8,9-Tetrahydro-5,6-epoxy-5H-benzocycloheptene;2,3,4,8B-tetrahydro-1aH-benzo[3,4]cyclohepta[1,2-b]oxirene

Suppliers and Price of 2,3,4,8b-Tetrahydro-1aH-1-oxa-benzo[a]cyclopropa[c]cycloheptene

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

American Custom Chemicals Corporation
2,3,4,8B-TETRAHYDRO-1AH-1-OXA-BENZO[A]CYCLOPROPA[C]CYCLOHEPTENE 95.00%
5MG
$ 499.07

Total 5 raw suppliers

Chemical Property of 2,3,4,8b-Tetrahydro-1aH-1-oxa-benzo[a]cyclopropa[c]cycloheptene

Chemical Property:

Boiling Point:70-72 °C(Press: 0.2 Torr)
PSA：12.53000
Density:1.114±0.06 g/cm3(Predicted)
LogP:2.46280
XLogP3:2.2
Hydrogen Bond Donor Count:0
Hydrogen Bond Acceptor Count:1
Rotatable Bond Count:0
Exact Mass:160.088815002
Heavy Atom Count:12
Complexity:178

Purity/Quality:

85.0-99.8% ^*data from raw suppliers

2,3,4,8B-TETRAHYDRO-1AH-1-OXA-BENZO[A]CYCLOPROPA[C]CYCLOHEPTENE 95.00% ^*data from reagent suppliers

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:: SDS file from LookChem

Useful:

Canonical SMILES:C1CC2C(O2)C3=CC=CC=C3C1

Technology Process of 2,3,4,8b-Tetrahydro-1aH-1-oxa-benzo[a]cyclopropa[c]cycloheptene

There total 9 articles about 2,3,4,8b-Tetrahydro-1aH-1-oxa-benzo[a]cyclopropa[c]cycloheptene which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 75.0%

: 7125-62-4
1,2-benzo-1,3-cycloheptadiene

: 4443-71-4,127641-88-7,127641-89-8
(rac)-5,6-epoxy-6,7,8,9-tetrahydro-5-benzocycloheptane

Guidance literature:: With 3-chloro-benzenecarboperoxoic acid; In chloroform; at 0 ℃;

Reference yield: 71.0%

: 7125-62-4
1,2-benzo-1,3-cycloheptadiene

: 4443-71-4
3,4-benzo-1,2-epoxy-1,3-cycloheptadiene

Guidance literature:: With 3-chloro-benzenecarboperoxoic acid; In dichloromethane; at 0 ℃; for 3h;
DOI:10.1021/ja00004a041

Reference yield:

: 35550-94-8,65915-63-1,79416-49-2,138381-73-4
1-benzosuberol

: 4443-71-4
3,4-benzo-1,2-epoxy-1,3-cycloheptadiene

Guidance literature:: Multi-step reaction with 2 steps

1: 90 percent / p-toluenesulfonic acid / benzene / 24 h / Heating

2: 71 percent / m-chloroperbenzoic acid / CH₂Cl₂ / 3 h / 0 °C

With toluene-4-sulfonic acid; 3-chloro-benzenecarboperoxoic acid; In dichloromethane; benzene;
DOI:10.1021/ja00004a041