tert-butyl [(1S,6R)-6-(7-methoxybenzo[d][1,3]dioxol-5-yl)-4-oxocyclohex-2-en-1-yl]carbamate

Base Information

Chemical Name:tert-butyl [(1S,6R)-6-(7-methoxybenzo[d][1,3]dioxol-5-yl)-4-oxocyclohex-2-en-1-yl]carbamate
CAS No.:1402069-89-9
Molecular Formula:C₁₉H₂₃NO₆
Molecular Weight:361.395
Hs Code.:

Synonyms:tert-butyl [(1S,6R)-6-(7-methoxybenzo[d][1,3]dioxol-5-yl)-4-oxocyclohex-2-en-1-yl]carbamate

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Chemical Property of tert-butyl [(1S,6R)-6-(7-methoxybenzo[d][1,3]dioxol-5-yl)-4-oxocyclohex-2-en-1-yl]carbamate

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Technology Process of tert-butyl [(1S,6R)-6-(7-methoxybenzo[d][1,3]dioxol-5-yl)-4-oxocyclohex-2-en-1-yl]carbamate

There total 14 articles about tert-butyl [(1S,6R)-6-(7-methoxybenzo[d][1,3]dioxol-5-yl)-4-oxocyclohex-2-en-1-yl]carbamate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: C₂₂H₃₃NO₆Si

: 1402069-89-9
tert-butyl [(1S,6R)-6-(7-methoxybenzo[d][1,3]dioxol-5-yl)-4-oxocyclohex-2-en-1-yl]carbamate

: C₁₉H₂₃NO₆

Guidance literature:: With 4-methoxypyridine N-oxide; 1-hydroxy-3H-benz[d][1,2]iodoxole-1,3-dione; In dimethyl sulfoxide; at 20 ℃; for 1h;
DOI:10.1016/j.tet.2018.08.016

Reference yield:

: 1402069-79-7
(2R,3R,E)-Methyl 2-(tert-butoxycarbonylamino)-3-(7-methoxybenzo[d]-ACHTUNGTRENUNG[1,3]dioxol-5-yl)hex-4-enoate

: 1402069-89-9
tert-butyl [(1S,6R)-6-(7-methoxybenzo[d][1,3]dioxol-5-yl)-4-oxocyclohex-2-en-1-yl]carbamate

Guidance literature:: Multi-step reaction with 4 steps

1: perchloric acid; palladium diacetate; p-benzoquinone / water; acetonitrile / 6 h / 20 °C

2: potassium tert-butylate / tetrahydrofuran / 0.5 h / 0 °C

3: camphor-10-sulfonic acid / toluene / 4 h / 80 °C

4: diisobutylaluminium hydride

With perchloric acid; camphor-10-sulfonic acid; potassium tert-butylate; palladium diacetate; diisobutylaluminium hydride; p-benzoquinone; In tetrahydrofuran; water; toluene; acetonitrile; 1: Wacker oxidation;
DOI:10.1002/chem.201201649

Reference yield:

: 1402069-91-3
C₁₉H₂₅NO₇

: 1402069-89-9
tert-butyl [(1S,6R)-6-(7-methoxybenzo[d][1,3]dioxol-5-yl)-4-oxocyclohex-2-en-1-yl]carbamate

Guidance literature:: Multi-step reaction with 5 steps

1: methanol; diethyl ether / 1 h

2: perchloric acid; palladium diacetate; p-benzoquinone / water; acetonitrile / 6 h / 20 °C

3: potassium tert-butylate / tetrahydrofuran / 0.5 h / 0 °C

4: camphor-10-sulfonic acid / toluene / 4 h / 80 °C

5: diisobutylaluminium hydride

With perchloric acid; camphor-10-sulfonic acid; potassium tert-butylate; palladium diacetate; diisobutylaluminium hydride; p-benzoquinone; In tetrahydrofuran; methanol; diethyl ether; water; toluene; acetonitrile; 2: Wacker oxidation;
DOI:10.1002/chem.201201649