2,5-anhydro-3,4,6-tri-O-benzyl-2-deoxy-2-(pent-4-enoylamido)-N-(1,1,3,3-tetramethylbutyl)-D-talo-hexonamide

Base Information

Chemical Name:2,5-anhydro-3,4,6-tri-O-benzyl-2-deoxy-2-(pent-4-enoylamido)-N-(1,1,3,3-tetramethylbutyl)-D-talo-hexonamide
CAS No.:1047990-80-6
Molecular Formula:C₄₀H₅₂N₂O₅
Molecular Weight:640.863
Hs Code.:

Synonyms:2,5-anhydro-3,4,6-tri-O-benzyl-2-deoxy-2-(pent-4-enoylamido)-N-(1,1,3,3-tetramethylbutyl)-D-talo-hexonamide

Suppliers and Price of 2,5-anhydro-3,4,6-tri-O-benzyl-2-deoxy-2-(pent-4-enoylamido)-N-(1,1,3,3-tetramethylbutyl)-D-talo-hexonamide

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 0 raw suppliers

Chemical Property of 2,5-anhydro-3,4,6-tri-O-benzyl-2-deoxy-2-(pent-4-enoylamido)-N-(1,1,3,3-tetramethylbutyl)-D-talo-hexonamide

Chemical Property:

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:

Useful:

Technology Process of 2,5-anhydro-3,4,6-tri-O-benzyl-2-deoxy-2-(pent-4-enoylamido)-N-(1,1,3,3-tetramethylbutyl)-D-talo-hexonamide

There total 2 articles about 2,5-anhydro-3,4,6-tri-O-benzyl-2-deoxy-2-(pent-4-enoylamido)-N-(1,1,3,3-tetramethylbutyl)-D-talo-hexonamide which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 53.0%

: 591-80-0
pent-4-enoic acid

: 909870-16-2
(3R,4S,5R)-3,4-di-O-benzyl-5-(benzyloxymethyl)-1-pyrroline

: 14542-93-9
1,1,3,3-tetramethylbutane isonitrile

: 1047990-80-6
2,5-anhydro-3,4,6-tri-O-benzyl-2-deoxy-2-(pent-4-enoylamido)-N-(1,1,3,3-tetramethylbutyl)-D-talo-hexonamide

: 1047990-79-3
2,5-anhydro-3,4,6-tri-O-benzyl-2-deoxy-2-(pent-4-enoylamido)-N-(1,1,3,3-tetramethylbutyl)-D-galacto-hexonamide

Guidance literature:: With indium(III) chloride; In acetonitrile; at 0 - 20 ℃; optical yield given as %de; diastereoselective reaction; Inert atmosphere;
DOI:10.1002/ejoc.200800340

Reference yield:

: 909870-15-1
2,3,5-tri-O-benzyl-4-deoxy-4-azido-D-lyxose

: 1047990-80-6
2,5-anhydro-3,4,6-tri-O-benzyl-2-deoxy-2-(pent-4-enoylamido)-N-(1,1,3,3-tetramethylbutyl)-D-talo-hexonamide

Guidance literature:: Multi-step reaction with 2 steps

1: trimethylphosphane / methanol; toluene / 3 h / 0 °C / Inert atmosphere

2: indium(III) chloride / acetonitrile / 20 h / 0 - 5 °C / Inert atmosphere

With indium(III) chloride; trimethylphosphane; In methanol; toluene; acetonitrile; 2: |Ugi Condensation;
DOI:10.1002/ejoc.201200923