1,3,4-tri-O-acetyl-6-bromo-2,6-dideoxy-2-(p-methoxybenzylideneamino)-β-D-glucopyranose

Base Information

Chemical Name:1,3,4-tri-O-acetyl-6-bromo-2,6-dideoxy-2-(p-methoxybenzylideneamino)-β-D-glucopyranose
CAS No.:63064-73-3
Molecular Formula:C₂₀H₂₄BrNO₈
Molecular Weight:486.316
Hs Code.:

Synonyms:1,3,4-tri-O-acetyl-6-bromo-2,6-dideoxy-2-(p-methoxybenzylideneamino)-β-D-glucopyranose

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Chemical Property of 1,3,4-tri-O-acetyl-6-bromo-2,6-dideoxy-2-(p-methoxybenzylideneamino)-β-D-glucopyranose

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Technology Process of 1,3,4-tri-O-acetyl-6-bromo-2,6-dideoxy-2-(p-methoxybenzylideneamino)-β-D-glucopyranose

There total 5 articles about 1,3,4-tri-O-acetyl-6-bromo-2,6-dideoxy-2-(p-methoxybenzylideneamino)-β-D-glucopyranose which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 46.0%

: 61289-75-6
1,3,4-tri-O-acetyl-6-azido-2,6-dideoxy-2-(p-methoxybenzylideneamino)-β-D-glucopyranose

: 63064-73-3
1,3,4-tri-O-acetyl-6-bromo-2,6-dideoxy-2-(p-methoxybenzylideneamino)-β-D-glucopyranose

Guidance literature:: With hydrogen bromide; In dichloromethane; at -20 ℃; for 0.0333333h;
DOI:10.1246/bcsj.53.3259

Reference yield:

: 77059-32-6
benzyl ((2S,3R,4R,5S,6R)-2,4,5-trihydroxy-6-(hydroxymethyl)tetrahydro-2H-pyran-3-yl)carbamate

: 63064-73-3
1,3,4-tri-O-acetyl-6-bromo-2,6-dideoxy-2-(p-methoxybenzylideneamino)-β-D-glucopyranose

Guidance literature:: Multi-step reaction with 5 steps

1: 51 percent / pyridine / 18 h / -20 °C

2: 78 percent / sodium azide / dimethylformamide / 0.33 h / 135 °C

3: 1.) aq. HCl, 2.) aq. NaOH, p-anisaldehyde / 1.) 90 deg C, 3 h, 2.) ethanol, RT, 30 min

4: 67 percent / pyridine / Ambient temperature

5: 46 percent / HBr / CH₂Cl₂ / 0.03 h / -20 °C

With hydrogenchloride; sodium hydroxide; sodium azide; hydrogen bromide; 4-methoxy-benzaldehyde; In pyridine; dichloromethane; N,N-dimethyl-formamide;
DOI:10.1246/bcsj.53.3259

Reference yield:

: 77020-22-5
6-azido-2-(benzyloxycarbonylamino)-2,6-dideoxy-α-D-glucopyranose

: 63064-73-3
1,3,4-tri-O-acetyl-6-bromo-2,6-dideoxy-2-(p-methoxybenzylideneamino)-β-D-glucopyranose

Guidance literature:: Multi-step reaction with 3 steps

1: 1.) aq. HCl, 2.) aq. NaOH, p-anisaldehyde / 1.) 90 deg C, 3 h, 2.) ethanol, RT, 30 min

2: 67 percent / pyridine / Ambient temperature

3: 46 percent / HBr / CH₂Cl₂ / 0.03 h / -20 °C

With hydrogenchloride; sodium hydroxide; hydrogen bromide; 4-methoxy-benzaldehyde; In pyridine; dichloromethane;
DOI:10.1246/bcsj.53.3259