(3-((4R,5R)-2,2-dimethyl-5-tetradecyl-1,3-dioxolan-4-yl)propyl)triphenyl phosphonium iodide

Base Information

Chemical Name:(3-((4R,5R)-2,2-dimethyl-5-tetradecyl-1,3-dioxolan-4-yl)propyl)triphenyl phosphonium iodide
CAS No.:1449471-82-2
Molecular Formula:C₄₀H₅₈O₂P*I
Molecular Weight:728.778
Hs Code.:

Synonyms:(3-((4R,5R)-2,2-dimethyl-5-tetradecyl-1,3-dioxolan-4-yl)propyl)triphenyl phosphonium iodide

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Chemical Property of (3-((4R,5R)-2,2-dimethyl-5-tetradecyl-1,3-dioxolan-4-yl)propyl)triphenyl phosphonium iodide

Chemical Property:

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Technology Process of (3-((4R,5R)-2,2-dimethyl-5-tetradecyl-1,3-dioxolan-4-yl)propyl)triphenyl phosphonium iodide

There total 6 articles about (3-((4R,5R)-2,2-dimethyl-5-tetradecyl-1,3-dioxolan-4-yl)propyl)triphenyl phosphonium iodide which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 84.0%

: 1449471-84-4
3-((4R,5R)-2,2-dimethyl-5-tetradecyl-1,3-dioxolan-4-yl)propan-1-ol

: 603-35-0
triphenylphosphine

: 1449471-82-2
(3-((4R,5R)-2,2-dimethyl-5-tetradecyl-1,3-dioxolan-4-yl)propyl)triphenyl phosphonium iodide

Guidance literature:: With 1H-imidazole; iodine; In dichloromethane; at 0 - 20 ℃; for 2.5h;
DOI:10.1002/anie.201208403

Reference yield:

: 112-71-0
1-Bromotetradecane

: 1449471-82-2
(3-((4R,5R)-2,2-dimethyl-5-tetradecyl-1,3-dioxolan-4-yl)propyl)triphenyl phosphonium iodide

Guidance literature:: Multi-step reaction with 6 steps

1.1: magnesium; iodine / diethyl ether / 2 h / 20 °C

1.2: 2 h / 0 - 20 °C

2.1: propionic acid / benzene / 2 h / 150 °C

3.1: methanesulfonamide; AD-mix β / tert-butyl alcohol; water / 19 h / 0 °C

4.1: lithium aluminium tetrahydride / diethyl ether / 2 h / 0 °C / Reflux

5.1: toluene-4-sulfonic acid / toluene / 60 °C

6.1: 1H-imidazole; iodine / dichloromethane / 2.5 h / 0 - 20 °C

With 1H-imidazole; lithium aluminium tetrahydride; methanesulfonamide; AD-mix β; iodine; toluene-4-sulfonic acid; magnesium; propionic acid; In diethyl ether; dichloromethane; water; toluene; tert-butyl alcohol; benzene; 2.1: |Johnson-Claisen Rearrangement;
DOI:10.1002/anie.201208403

Reference yield:

: 909270-40-2
(R)-5-((R)-1-hydroxypentadecyl)-dihydrofuran-2(3H)-one

: 1449471-82-2
(3-((4R,5R)-2,2-dimethyl-5-tetradecyl-1,3-dioxolan-4-yl)propyl)triphenyl phosphonium iodide

Guidance literature:: Multi-step reaction with 3 steps

1: lithium aluminium tetrahydride / diethyl ether / 2 h / 0 °C / Reflux

2: toluene-4-sulfonic acid / toluene / 60 °C

3: 1H-imidazole; iodine / dichloromethane / 2.5 h / 0 - 20 °C

With 1H-imidazole; lithium aluminium tetrahydride; iodine; toluene-4-sulfonic acid; In diethyl ether; dichloromethane; toluene;
DOI:10.1002/anie.201208403