Technology Process of C56H98O7Si3
There total 29 articles about C56H98O7Si3 which
guide to synthetic route it.
The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:
synthetic route:
- Guidance literature:
-
triethyl((2R,3R,5S,6S)-1-iodo-6-(4-methoxybenzyloxy)-2,5-dimethylheptan-3-yloxy)silane;
With
tert.-butyl lithium; 9-methoxy-9-BBN;
In
tetrahydrofuran; diethyl ether; hexane; pentane;
at -78 - 20 ℃;
for 1.08333h;
C33H57IO4Si2;
With
(1,1'-bis(diphenylphosphino)ferrocene)palladium(II) dichloride; triphenyl-arsane; caesium carbonate;
In
tetrahydrofuran; diethyl ether; hexane; water; N,N-dimethyl-formamide; pentane;
at 20 ℃;
DOI:10.1016/j.tet.2011.07.066
- Guidance literature:
-
Multi-step reaction with 8 steps
1.1: 2,6-dimethylpyridine / dichloromethane / 1.5 h / -78 - 20 °C
2.1: pyridinium p-toluenesulfonate / methanol; dichloromethane / 0.25 h
3.1: sodium hydrogencarbonate; Dess-Martin periodane / dichloromethane / 1 h
4.1: tin(IV) chloride / dichloromethane / 0.75 h / -78 °C
4.2: 3 h / -78 °C
4.3: -78 - 20 °C
5.1: 2,6-dimethylpyridine / dichloromethane / 1.5 h / 0 - 20 °C
6.1: pyridine; pyridine hydrofluoride / tetrahydrofuran / 0.5 h
7.1: scandium tris(trifluoromethanesulfonate) / toluene / 3 h
8.1: tert.-butyl lithium; 9-methoxy-9-BBN / tetrahydrofuran; diethyl ether; hexane; pentane / 1.08 h / -78 - 20 °C
8.2: 20 °C
With
pyridine; 2,6-dimethylpyridine; pyridine hydrofluoride; tert.-butyl lithium; pyridinium p-toluenesulfonate; tin(IV) chloride; sodium hydrogencarbonate; Dess-Martin periodane; 9-methoxy-9-BBN; scandium tris(trifluoromethanesulfonate);
In
tetrahydrofuran; methanol; diethyl ether; hexane; dichloromethane; toluene; pentane;
4.1: Sakurai reaction / 4.2: Sakurai reaction / 8.2: Suzuki-Miyaura coupling;
DOI:10.1016/j.tet.2011.07.066
- Guidance literature:
-
Multi-step reaction with 9 steps
1.1: pyridinium p-toluenesulfonate; toluene-4-sulfonic acid / methanol / 2 h
2.1: 2,6-dimethylpyridine / dichloromethane / 1.5 h / -78 - 20 °C
3.1: pyridinium p-toluenesulfonate / methanol; dichloromethane / 0.25 h
4.1: sodium hydrogencarbonate; Dess-Martin periodane / dichloromethane / 1 h
5.1: tin(IV) chloride / dichloromethane / 0.75 h / -78 °C
5.2: 3 h / -78 °C
5.3: -78 - 20 °C
6.1: 2,6-dimethylpyridine / dichloromethane / 1.5 h / 0 - 20 °C
7.1: pyridine; pyridine hydrofluoride / tetrahydrofuran / 0.5 h
8.1: scandium tris(trifluoromethanesulfonate) / toluene / 3 h
9.1: tert.-butyl lithium; 9-methoxy-9-BBN / tetrahydrofuran; diethyl ether; hexane; pentane / 1.08 h / -78 - 20 °C
9.2: 20 °C
With
pyridine; 2,6-dimethylpyridine; pyridine hydrofluoride; tert.-butyl lithium; pyridinium p-toluenesulfonate; tin(IV) chloride; sodium hydrogencarbonate; Dess-Martin periodane; toluene-4-sulfonic acid; 9-methoxy-9-BBN; scandium tris(trifluoromethanesulfonate);
In
tetrahydrofuran; methanol; diethyl ether; hexane; dichloromethane; toluene; pentane;
5.1: Sakurai reaction / 5.2: Sakurai reaction / 9.2: Suzuki-Miyaura coupling;
DOI:10.1016/j.tet.2011.07.066
