meso-Tetratolylporphyrin-Mn(III)chloride

Base Information

• Chemical Name: meso-Tetratolylporphyrin-Mn(III)chloride
• CAS No.: 43145-44-4
• Molecular Formula: C₄₈H₃₆ClMnN₄
• Molecular Weight: 759.232
• Mol file: 43145-44-4.mol

Synonyms:Manganese,chloro[5,10,15,20-tetrakis(4-methylphenyl)-21H,23H-porphinato(2-)-N21,N22,N23,N24]-,(SP-5-12)-; 21H,23H-Porphine, 5,10,15,20-tetrakis(4-methylphenyl)-, manganesecomplex; Chloro(tetra-p-methylphenylporphyrinato)manganese;[5,10,15,20-Tetrakis(p-methylphenyl)porphinato]manganese(III) chloride

Chemical Property of meso-Tetratolylporphyrin-Mn(III)chloride

Chemical Property:

Purity/Quality:

98.5% ^*data from raw suppliers

5,10,15,20-Tetra(4-methylphenyl)-21H,23H-porphinemanganese(III)chloride 97% ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of meso-Tetratolylporphyrin-Mn(III)chloride

There total 2 articles about meso-Tetratolylporphyrin-Mn(III)chloride which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

5,10,15,20-tetra(p-tolyl)porphyrin (14527-51-6) → C48H36ClMnN4 (43145-44-4)

Guidance literature:

With manganese(ll) chloride; In N,N-dimethyl-formamide; at 20 ℃;

DOI:10.1142/S1088424613500612

Reference yield:

Mn(4+)*C20H8N4(C7H7)4(2-)*O2(2-)=MnC20H8N4(C7H7)4O2 (67368-91-6) + sulfur dioxide (7446-09-5,12143-17-8,89125-89-3) → C48H36ClMnN4 (43145-44-4)

Guidance literature:

In acetonitrile; byproducts: SO4(2-); soln. of SO2 added to soln. of the generated Mn(IV) peroxo complex; UV; Kinetics;

Reference yield: 89.0%

C48H36ClMnN4 (43145-44-4) + triphenylphosphine (603-35-0) → [5,10,15,20-tetrakis(4-methylphenyl)porphyrinato](triphenylphosphan)manganese(III) hexafluorophosphate

Guidance literature:

With ammonium hexafluorophosphate; In toluene; byproducts: NH4Cl; 2 h, reflux; the solvent was removed in vac., PPh3 was removed in high vac. at 80 - 100 °C, the product was washed with hexane and crystd. from CH2Cl2/hexane by addn. of NH4PF6 in acetone, elem. anal.;

upstream raw materials:

Mn⁽⁴⁺⁾*C₂₀H₈N₄(C₇H₇)4^(2-)*O₂^(2-)=MnC₂₀H₈N₄(C₇H₇)4O₂

sulfur dioxide

5,10,15,20-tetra(p-tolyl)porphyrin

Downstream raw materials:

Mn⁽⁴⁺⁾*C₂₀H₈N₄(C₇H₇)4^(2-)*O₂^(2-)=MnC₂₀H₈N₄(C₇H₇)4O₂

phthalimido[5,10,15,20-tetrakis(4-methylphenyl)porphyrinato]manganese(III)

Refernces