[3-allyloxy-5-(3-allyloxy-5-{3-allyloxy-5-[3-allyloxy-5-(3-allyloxy-5-hydroxymethyl-benzylsulfanylmethyl)-benzylsulfanylmethyl]-benzylsulfanylmethyl}-benzylsulfanylmethyl)-phenyl]-methanol

Base Information

• Chemical Name: [3-allyloxy-5-(3-allyloxy-5-{3-allyloxy-5-[3-allyloxy-5-(3-allyloxy-5-hydroxymethyl-benzylsulfanylmethyl)-benzylsulfanylmethyl]-benzylsulfanylmethyl}-benzylsulfanylmethyl)-phenyl]-methanol
• CAS No.: 872115-29-2
• Molecular Formula: C₅₅H₆₂O₇S₄
• Molecular Weight: 963.357
• Mol file: 872115-29-2.mol

Synonyms:[3-allyloxy-5-(3-allyloxy-5-{3-allyloxy-5-[3-allyloxy-5-(3-allyloxy-5-hydroxymethyl-benzylsulfanylmethyl)-benzylsulfanylmethyl]-benzylsulfanylmethyl}-benzylsulfanylmethyl)-phenyl]-methanol

Chemical Property of [3-allyloxy-5-(3-allyloxy-5-{3-allyloxy-5-[3-allyloxy-5-(3-allyloxy-5-hydroxymethyl-benzylsulfanylmethyl)-benzylsulfanylmethyl]-benzylsulfanylmethyl}-benzylsulfanylmethyl)-phenyl]-methanol

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of [3-allyloxy-5-(3-allyloxy-5-{3-allyloxy-5-[3-allyloxy-5-(3-allyloxy-5-hydroxymethyl-benzylsulfanylmethyl)-benzylsulfanylmethyl]-benzylsulfanylmethyl}-benzylsulfanylmethyl)-phenyl]-methanol

There total 6 articles about [3-allyloxy-5-(3-allyloxy-5-{3-allyloxy-5-[3-allyloxy-5-(3-allyloxy-5-hydroxymethyl-benzylsulfanylmethyl)-benzylsulfanylmethyl]-benzylsulfanylmethyl}-benzylsulfanylmethyl)-phenyl]-methanol which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

C65H78O9S4 (872115-34-9) → [3-allyloxy-5-(3-allyloxy-5-{3-allyloxy-5-[3-allyloxy-5-(3-allyloxy-5-hydroxymethyl-benzylsulfanylmethyl)-benzylsulfanylmethyl]-benzylsulfanylmethyl}-benzylsulfanylmethyl)-phenyl]-methanol (872115-29-2)

Guidance literature:

With methanol; toluene-4-sulfonic acid; In dichloromethane; at 20 ℃;

DOI:10.1246/bcsj.78.1773

Reference yield:

1-allyloxy-3-bromomethyl-5-hydroxymethylbenzene (872115-27-0) + Thioacetic acid S-{3-[3-(3-acetylsulfanylmethyl-5-allyloxy-benzylsulfanylmethyl)-5-allyloxy-benzylsulfanylmethyl]-5-allyloxy-benzyl} ester → [3-allyloxy-5-(3-allyloxy-5-{3-allyloxy-5-[3-allyloxy-5-(3-allyloxy-5-hydroxymethyl-benzylsulfanylmethyl)-benzylsulfanylmethyl]-benzylsulfanylmethyl}-benzylsulfanylmethyl)-phenyl]-methanol (872115-29-2)

Guidance literature:

With sodium hydroxide; In tetrahydrofuran; methanol; water; at 0 - 20 ℃;

DOI:10.1246/bcsj.78.1773

Reference yield:

[5-(prop-2-en-1-yloxy)benzene-1,3-diyl]dimethanol (156204-47-6) → [3-allyloxy-5-(3-allyloxy-5-{3-allyloxy-5-[3-allyloxy-5-(3-allyloxy-5-hydroxymethyl-benzylsulfanylmethyl)-benzylsulfanylmethyl]-benzylsulfanylmethyl}-benzylsulfanylmethyl)-phenyl]-methanol (872115-29-2)

Guidance literature:

Multi-step reaction with 5 steps

1: 28 percent / phosphorus tribromide; pyridine / CH₂Cl₂ / 24 h / 20 °C

2: 2.75 g / NaOH / tetrahydrofuran; methanol; H₂O / 0 - 20 °C

3: 74 percent / phosphorus tribromide; pyridine / CH₂Cl₂ / 24 h / 20 °C

4: 1,8-diazabicyclo[5.4.0]undec-7-ene / tetrahydrofuran / 5 h / 20 °C

5: 877 mg / NaOH / tetrahydrofuran; methanol; H₂O / 0 - 20 °C

With pyridine; sodium hydroxide; phosphorus tribromide; 1,8-diazabicyclo[5.4.0]undec-7-ene; In tetrahydrofuran; methanol; dichloromethane; water;

DOI:10.1246/bcsj.78.1773

upstream raw materials:

1-allyloxy-3-bromomethyl-5-hydroxymethylbenzene

C₆₅H₇₈O₉S₄

[5-(prop-2-en-1-yloxy)benzene-1,3-diyl]dimethanol

1-allyloxy-3,5-bis(bromomethyl)benzene

Downstream raw materials:

{3-allyloxy-5-[3-allyloxy-5-(3-allyloxy-5-{3-allyloxy-5-[3-allyloxy-5-(tetrahydro-pyran-2-yloxymethyl)-benzylsulfanylmethyl]-benzylsulfanylmethyl}-benzylsulfanylmethyl)-benzylsulfanylmethyl]-phenyl}-methanol

C₆₅H₇₈O₉S₄

C₅₅H₆₀Br₂O₅S₄

Thioacetic acid S-{3-allyloxy-5-[3-allyloxy-5-(3-allyloxy-5-{3-allyloxy-5-[3-allyloxy-5-(tetrahydro-pyran-2-yloxymethyl)-benzylsulfanylmethyl]-benzylsulfanylmethyl}-benzylsulfanylmethyl)-benzylsulfanylmethyl]-benzyl} ester