(1S,6S)-benzyl 3,3,5,5-tetraphenyl-2,4-dioxa-7-aza-3-silabicyclo[4.2.1]nonane-7-carboxylate

Base Information

Chemical Name:(1S,6S)-benzyl 3,3,5,5-tetraphenyl-2,4-dioxa-7-aza-3-silabicyclo[4.2.1]nonane-7-carboxylate
CAS No.:1434302-15-4
Molecular Formula:C₃₇H₃₃NO₄Si
Molecular Weight:583.759
Hs Code.:

Synonyms:(1S,6S)-benzyl 3,3,5,5-tetraphenyl-2,4-dioxa-7-aza-3-silabicyclo[4.2.1]nonane-7-carboxylate

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Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of (1S,6S)-benzyl 3,3,5,5-tetraphenyl-2,4-dioxa-7-aza-3-silabicyclo[4.2.1]nonane-7-carboxylate

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Technology Process of (1S,6S)-benzyl 3,3,5,5-tetraphenyl-2,4-dioxa-7-aza-3-silabicyclo[4.2.1]nonane-7-carboxylate

There total 2 articles about (1S,6S)-benzyl 3,3,5,5-tetraphenyl-2,4-dioxa-7-aza-3-silabicyclo[4.2.1]nonane-7-carboxylate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 87.0%

: 1434302-10-9
(2S,4S)-benzyl 4-hydroxy-2-(hydroxydiphenylmethyl)pyrrolidine-1-carboxylate

: 80-10-4
diphenylsilyl dichloride

: 1434302-15-4
(1S,6S)-benzyl 3,3,5,5-tetraphenyl-2,4-dioxa-7-aza-3-silabicyclo[4.2.1]nonane-7-carboxylate

Guidance literature:: With 1H-imidazole; In N,N-dimethyl-formamide; at 0 - 20 ℃; for 21h; Inert atmosphere;
DOI:10.1002/adsc.201200922

Reference yield:

: 13504-85-3
(2S,4R)-1-(benzyloxycarbonyl)-4-hydroxypyrrolidine-2-carboxylic acid

: 1434302-15-4
(1S,6S)-benzyl 3,3,5,5-tetraphenyl-2,4-dioxa-7-aza-3-silabicyclo[4.2.1]nonane-7-carboxylate

Guidance literature:: Multi-step reaction with 3 steps

1: diethylazodicarboxylate; triphenylphosphine / toluene; tetrahydrofuran / 5 h / 0 - 20 °C / Inert atmosphere

2: tetrahydrofuran; diethyl ether / 8.5 h / 0 - 20 °C / Inert atmosphere

3: 1H-imidazole / N,N-dimethyl-formamide / 21 h / 0 - 20 °C / Inert atmosphere

With 1H-imidazole; triphenylphosphine; diethylazodicarboxylate; In tetrahydrofuran; diethyl ether; N,N-dimethyl-formamide; toluene;
DOI:10.1002/adsc.201200922

Reference yield: 63.0%

: 1434302-15-4
(1S,6S)-benzyl 3,3,5,5-tetraphenyl-2,4-dioxa-7-aza-3-silabicyclo[4.2.1]nonane-7-carboxylate

: 1434302-19-8
(1S,6S)-3,3,5,5-tetraphenyl-2,4-dioxa-7-aza-3-silabicyclo[4.2.1]nonane

Guidance literature:: With palladium 10% on activated carbon; hydrogen; In tetrahydrofuran; methanol; at 20 ℃; for 18h;
DOI:10.1002/adsc.201200922