allyl 4,6‐O‐benzylidene‐2‐deoxy‐3‐methoxycarbonyl‐2‐(2,2,2‐trichloroethoxycarbonylamino)‐α‐D‐glucopyranoside

Base Information

• Chemical Name: allyl 4,6‐O‐benzylidene‐2‐deoxy‐3‐methoxycarbonyl‐2‐(2,2,2‐trichloroethoxycarbonylamino)‐α‐D‐glucopyranoside
• CAS No.: 1202384-99-3
• Molecular Formula: C₂₁H₂₄Cl₃NO₉
• Molecular Weight: 540.782
• Mol file: 1202384-99-3.mol

Synonyms:allyl 4,6‐O‐benzylidene‐2‐deoxy‐3‐methoxycarbonyl‐2‐(2,2,2‐trichloroethoxycarbonylamino)‐α‐D‐glucopyranoside

Chemical Property of allyl 4,6‐O‐benzylidene‐2‐deoxy‐3‐methoxycarbonyl‐2‐(2,2,2‐trichloroethoxycarbonylamino)‐α‐D‐glucopyranoside

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of allyl 4,6‐O‐benzylidene‐2‐deoxy‐3‐methoxycarbonyl‐2‐(2,2,2‐trichloroethoxycarbonylamino)‐α‐D‐glucopyranoside

There total 1 articles about allyl 4,6‐O‐benzylidene‐2‐deoxy‐3‐methoxycarbonyl‐2‐(2,2,2‐trichloroethoxycarbonylamino)‐α‐D‐glucopyranoside which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 100.0%

methyl chloroformate (79-22-1) + allyl 4,6-O-benzylidene-2-deoxy-2-(2,2,2-trichloroethoxycarbonylamino)-α-D-glucopyranoside (183388-21-8) → allyl 4,6‐O‐benzylidene‐2‐deoxy‐3‐methoxycarbonyl‐2‐(2,2,2‐trichloroethoxycarbonylamino)‐α‐D‐glucopyranoside (1202384-99-3)

Guidance literature:

With N,N,N,N,-tetramethylethylenediamine; In dichloromethane; at 0 ℃; for 1h;

DOI:10.1039/c9ob00104b

Reference yield: 76.0%

allyl 4,6‐O‐benzylidene‐2‐deoxy‐3‐methoxycarbonyl‐2‐(2,2,2‐trichloroethoxycarbonylamino)‐α‐D‐glucopyranoside (1202384-99-3) → allyl 4,6-O-benzylidene-2-deoxy-2-(2,2,2-trichloroethoxycarbonylamino)-α-D-glucopyranoside (183388-21-8)

Guidance literature:

With pyridine; acetic acid; lithium iodide; for 4h; chemoselective reaction; Reflux;

DOI:10.1016/j.tetlet.2009.09.174

Reference yield:

allyl 4,6‐O‐benzylidene‐2‐deoxy‐3‐methoxycarbonyl‐2‐(2,2,2‐trichloroethoxycarbonylamino)‐α‐D‐glucopyranoside (1202384-99-3) → C18H20Cl3NO9

Guidance literature:

With sodium acetate; acetic acid; palladium dichloride; In water; ethyl acetate; at 20 ℃; for 21h;

DOI:10.1039/c9ob00104b

upstream raw materials:

methyl chloroformate

allyl 4,6-O-benzylidene-2-deoxy-2-(2,2,2-trichloroethoxycarbonylamino)-α-D-glucopyranoside

Downstream raw materials:

allyl 4,6-O-benzylidene-2-deoxy-2-(2,2,2-trichloroethoxycarbonylamino)-α-D-glucopyranoside