Technology Process of C6H2(CH3)2(C(O)OCH3)(C2H2C(CH3)CHI)
There total 9 articles about C6H2(CH3)2(C(O)OCH3)(C2H2C(CH3)CHI) which
guide to synthetic route it.
The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:
synthetic route:
- Guidance literature:
-
C6H2(CH3)2(C(O)OCH3)C2H2C(CH3)CH(BO2CCH2N(CH3)CH2CO2);
With
sodium methylate;
In
tetrahydrofuran; methanol;
at 23 ℃;
for 0.25h;
Inert atmosphere;
With
iodine;
In
tetrahydrofuran; methanol;
at 23 ℃;
for 0.333333h;
Inert atmosphere;
DOI:10.1002/anie.201102688
- Guidance literature:
-
Multi-step reaction with 5 steps
1.1: sodium hydride / N,N-dimethyl-formamide; mineral oil / 0.5 h / 0 - 23 °C / Inert atmosphere
1.2: 12 h / 0 - 23 °C / Inert atmosphere
2.1: dichloro(1,1'-bis(diphenylphosphanyl)ferrocene)palladium(II)*CH2Cl2; potassium acetate / 1,4-dioxane / 18 h / 80 °C / Inert atmosphere
3.1: chloroamine-T; sodium iodide / tetrahydrofuran; water / 13 h / 0 - 23 °C / Inert atmosphere
4.1: potassium phosphate; dichloro(1,1'-bis(diphenylphosphanyl)ferrocene)palladium(II)*CH2Cl2 / dimethyl sulfoxide / 24 h / 45 °C / Inert atmosphere
5.1: sodium methylate / tetrahydrofuran; methanol / 0.25 h / 23 °C / Inert atmosphere
5.2: 0.33 h / 23 °C / Inert atmosphere
With
potassium phosphate; dichloro(1,1'-bis(diphenylphosphanyl)ferrocene)palladium(II)*CH2Cl2; sodium methylate; potassium acetate; chloroamine-T; sodium hydride; sodium iodide;
In
tetrahydrofuran; 1,4-dioxane; methanol; water; dimethyl sulfoxide; N,N-dimethyl-formamide; mineral oil;
DOI:10.1002/anie.201102688
- Guidance literature:
-
Multi-step reaction with 4 steps
1.1: dichloro(1,1'-bis(diphenylphosphanyl)ferrocene)palladium(II)*CH2Cl2; potassium acetate / 1,4-dioxane / 18 h / 80 °C / Inert atmosphere
2.1: chloroamine-T; sodium iodide / tetrahydrofuran; water / 13 h / 0 - 23 °C / Inert atmosphere
3.1: potassium phosphate; dichloro(1,1'-bis(diphenylphosphanyl)ferrocene)palladium(II)*CH2Cl2 / dimethyl sulfoxide / 24 h / 45 °C / Inert atmosphere
4.1: sodium methylate / tetrahydrofuran; methanol / 0.25 h / 23 °C / Inert atmosphere
4.2: 0.33 h / 23 °C / Inert atmosphere
With
potassium phosphate; dichloro(1,1'-bis(diphenylphosphanyl)ferrocene)palladium(II)*CH2Cl2; sodium methylate; potassium acetate; chloroamine-T; sodium iodide;
In
tetrahydrofuran; 1,4-dioxane; methanol; water; dimethyl sulfoxide;
DOI:10.1002/anie.201102688
