[Os(Sn(CH₃)3)Cl(CO)(P(C₆H₅)3)2]

Base Information

• Chemical Name: [Os(Sn(CH₃)3)Cl(CO)(P(C₆H₅)3)2]
• CAS No.: 174686-08-9
• Molecular Formula: C₄₀H₃₉ClOOsP₂Sn
• Molecular Weight: 942.06
• Mol file: 174686-08-9.mol

Synonyms:[Os(Sn(CH₃)3)Cl(CO)(P(C₆H₅)3)2]

Chemical Property of [Os(Sn(CH₃)3)Cl(CO)(P(C₆H₅)3)2]

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of [Os(Sn(CH₃)3)Cl(CO)(P(C₆H₅)3)2]

There total 1 articles about [Os(Sn(CH₃)3)Cl(CO)(P(C₆H₅)3)2] which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

hydridocarbonylchlorotris(triphenylphosphine)osmium(II) (16971-31-6,36007-23-5) + tri-n-butyl(vinyl)tin (7486-35-3) → [Os(Sn(CH3)3)Cl(CO)(P(C6H5)3)2] (174686-08-9)

Guidance literature:

In toluene; benzene; byproducts: C2H4; Irradiation (UV/VIS); N2; Sn-compd. refluxing in solvent mixt., Os-compd. addn., mixt. photolysis for 7 min (1000 W tungsten/halogen lamp), rapid soln. cooling (ice bath), pptn. on n-hexane addn.;

DOI:10.1016/0020-1693(95)04558-9

Reference yield: 84.0%

[Os(Sn(CH3)3)Cl(CO)(P(C6H5)3)2] (174686-08-9) → Os(Sn(CH3)3)Cl(CO)2(P(C6H5)3)2 (174686-12-5)

Guidance literature:

With carbon monoxide; In toluene; benzene; CO bubbling vigorously through Os-compd. soln. until colourless, solvent removal (reduced pressure); recrystn. from CH2Cl2/EtOH twice; elem. anal.;

DOI:10.1016/0020-1693(95)04558-9

Reference yield: 83.0%

[Os(Sn(CH3)3)Cl(CO)(P(C6H5)3)2] (174686-08-9) + 4-methylphenyl isocyanide (7175-47-5) → Os(Sn(CH3)3)Cl(CO)(CNC6H4CH3)(P(C6H5)3)2 (174686-14-7)

Guidance literature:

In toluene; benzene; org. compd. soln. (CH2Cl2) addn. to Os-compd. soln. (benzene/toluene), solvent removal (reduced pressure); residue recrystn. twice (CH2Cl2/EtOH); elem. anal.;

DOI:10.1016/0020-1693(95)04558-9

upstream raw materials:

hydridocarbonylchlorotris(triphenylphosphine)osmium(II)

tri-n-butyl(vinyl)tin

Downstream raw materials:

Os(Sn(CH₃)3)Cl(CO)2(P(C₆H₅)3)2

Os(Sn(CH₃)3)Cl(CO)(CNC₆H₄CH₃)(P(C₆H₅)3)2