Technology Process of C45H45NO7S4
There total 3 articles about C45H45NO7S4 which
guide to synthetic route it.
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synthetic route:
- Guidance literature:
-
N,N-dimethyl-formamide;
With
trichlorophosphate;
at 0 ℃;
for 1h;
C44H45NO6S4;
In
N,N-dimethyl-formamide;
at 0 - 20 ℃;
for 1h;
With
sodium hydroxide;
In
N,N-dimethyl-formamide;
pH=10;
DOI:10.1016/j.tet.2012.04.113
- Guidance literature:
-
Multi-step reaction with 5 steps
1.1: N-Bromosuccinimide / N,N-dimethyl-formamide / 25.5 h / 15 - 20 °C / Darkness
2.1: tetrakis(triphenylphosphine) palladium(0) / para-xylene / 24 h / Inert atmosphere; Reflux
3.1: N-Bromosuccinimide / N,N-dimethyl-formamide / 24 h / 20 °C / Darkness
4.1: tetrakis(triphenylphosphine) palladium(0) / para-xylene / 5 h / Inert atmosphere; Reflux
5.1: trichlorophosphate / 1 h / 0 °C
5.2: 1 h / 0 - 20 °C
5.3: pH 10
With
N-Bromosuccinimide; tetrakis(triphenylphosphine) palladium(0); trichlorophosphate;
In
para-xylene; N,N-dimethyl-formamide;
2.1: Stille coupling / 4.1: Stille coupling / 5.2: Vilsmeier-Haack reaction;
DOI:10.1016/j.tet.2012.04.113
- Guidance literature:
-
Multi-step reaction with 3 steps
1.1: N-Bromosuccinimide / N,N-dimethyl-formamide / 24 h / 20 °C / Darkness
2.1: tetrakis(triphenylphosphine) palladium(0) / para-xylene / 5 h / Inert atmosphere; Reflux
3.1: trichlorophosphate / 1 h / 0 °C
3.2: 1 h / 0 - 20 °C
3.3: pH 10
With
N-Bromosuccinimide; tetrakis(triphenylphosphine) palladium(0); trichlorophosphate;
In
para-xylene; N,N-dimethyl-formamide;
2.1: Stille coupling / 3.2: Vilsmeier-Haack reaction;
DOI:10.1016/j.tet.2012.04.113
