1-[(2-Propynyloxy)methyl]pyrene

Base Information

• Chemical Name: 1-[(2-Propynyloxy)methyl]pyrene
• CAS No.: 1115084-83-7
• Molecular Formula: C₂₀H₁₄O
• Molecular Weight: 270.331
• Mol file: 1115084-83-7.mol

Synonyms:1-((prop-2-yn-1-yloxy)methyl)-pyrene

Chemical Property of 1-[(2-Propynyloxy)methyl]pyrene

Chemical Property:

• Melting Point: 83.0 to 87.0 °C
• Boiling Point: 461.3±20.0 °C(Predicted)
• Density: 1.240±0.06 g/cm3(Predicted)

Purity/Quality:

99% ^*data from raw suppliers

1-[(2-Propynyloxy)methyl]pyrene ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of 1-[(2-Propynyloxy)methyl]pyrene

There total 6 articles about 1-[(2-Propynyloxy)methyl]pyrene which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 99.0%

1-pyrenemethanol (24463-15-8) + propargyl bromide (106-96-7) → 1-((prop-2-yn-1-yloxy)methyl)-pyrene (1115084-83-7)

Guidance literature:

1-pyrenemethanol; With sodium hydride; In tetrahydrofuran; at 0 ℃; for 1h; Inert atmosphere;

propargyl bromide; In tetrahydrofuran; toluene; at 0 - 20 ℃; for 16h; Inert atmosphere; Darkness;

DOI:10.1002/chem.202101003

Reference yield: 90.0%

1-pyrenemethanol (24463-15-8) + 2-propynyl chloride (624-65-7) → 1-((prop-2-yn-1-yloxy)methyl)-pyrene (1115084-83-7)

Guidance literature:

1-pyrenemethanol; With sodium hydride; In N,N-dimethyl-formamide; at 0 - 20 ℃; for 1.16667h; Inert atmosphere;

2-propynyl chloride; In N,N-dimethyl-formamide; at 0 - 20 ℃; Inert atmosphere;

DOI:10.1039/C8NJ03216E

Reference yield:

1-(bromomethyl)pyrene (69795-71-7) + propargyl bromide (106-96-7) → 1-((prop-2-yn-1-yloxy)methyl)-pyrene (1115084-83-7)

Guidance literature:

propargyl bromide; With sodium hydride; In tetrahydrofuran; at 0 - 20 ℃; for 0.5h; Inert atmosphere;

1-(bromomethyl)pyrene; In tetrahydrofuran; at 0 - 20 ℃; Inert atmosphere;

DOI:10.1002/chem.201700607

upstream raw materials:

pyrene-1-aldehyde

propargyl bromide

1-pyrenemethanol

1-(bromomethyl)pyrene

Downstream raw materials:

1-benzyl-4-((pyren-1-ylmethoxy)methyl)-1H-1,2,3-triazole

C₁₁₁H₁₁₆N₁₀O₁₉

2-[2,4-di-(tert)-butylphenyl]-9-[(1-{2-oxo-2-[15-({4-[(pyren-1-ylmethoxy)methyl]-1H-1,2,3-triazol-1-yl}acetyl)-7,11,18,21-tetraoxa-3,15-diazatrispiro[5.2.2.512.29.26]henicos-3-yl]ethyl}-1H-1,2,3-triazol-4-yl)methyl]isoquinolino[4’,5’,6’: 6,5,10]anthra[2,1,9-def]isoquinoline-1,3,8,10(2H,9H)tetrone

Refernces

• 1、 Bektas, Semiha,Ciftci, Mustafa,Yagci, Yusuf. "Hyperbranched polymers by visible light induced self-condensing vinyl polymerization and their modifications". . p. 6751 - 6757. Retrieved 2013.
• 2、 Chen, Kuan-Hao,Lu, Cheng-Yi,Cheng, Hsiu-Jung,Chen, Shau-Jiun,Hu, Ching-Han,Wu, An-Tai. "A pyrenyl-appended triazole-based ribose as a fluorescent sensor for Hg2+ ion". . p. 2557 - 2561. Retrieved 2010.