allyl 3,6-di-O-benzyl-2-deoxy-4-O-methyl-2-phthalimido-β-D-glucopyranoside

Base Information

Chemical Name:allyl 3,6-di-O-benzyl-2-deoxy-4-O-methyl-2-phthalimido-β-D-glucopyranoside
CAS No.:152157-72-7
Molecular Formula:C₃₂H₃₃NO₇
Molecular Weight:543.617
Hs Code.:

Synonyms:allyl 3,6-di-O-benzyl-2-deoxy-4-O-methyl-2-phthalimido-β-D-glucopyranoside

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Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of allyl 3,6-di-O-benzyl-2-deoxy-4-O-methyl-2-phthalimido-β-D-glucopyranoside

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Technology Process of allyl 3,6-di-O-benzyl-2-deoxy-4-O-methyl-2-phthalimido-β-D-glucopyranoside

There total 1 articles about allyl 3,6-di-O-benzyl-2-deoxy-4-O-methyl-2-phthalimido-β-D-glucopyranoside which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 71.0%

: 186581-53-3,908094-01-9,334-88-3
diazomethane

: 89067-88-9
allyl-3,6-di-O-benzyl-2-deoxy-2-N-phthalimido-β-D-glucopyranoside

: 152157-72-7
allyl 3,6-di-O-benzyl-2-deoxy-4-O-methyl-2-phthalimido-β-D-glucopyranoside

Guidance literature:: With boron trifluoride diethyl etherate; In dichloromethane; at 0 - 5 ℃;
DOI:10.1016/0008-6215(93)84087-M

Reference yield:

: 152157-72-7
allyl 3,6-di-O-benzyl-2-deoxy-4-O-methyl-2-phthalimido-β-D-glucopyranoside

: 3,6-di-O-benzyl-2-deoxy-4-O-methyl-2-phthalimido-α,β-D-glucopyranosyl chloride

Guidance literature:: Multi-step reaction with 2 steps

1: 1.) 1,8-diazabicyclo<2.2.2>octane, 2.) HgO, HgCl₂ / 1.) tris(triphenylphosphine)rhodium(I) chloride / 1.) EtOH, benzene, H₂O, reflux, 30 h, 2.) acetone, H₂O, 2 h

2: N,N-dimethyl(chloromethylene)ammonium chloride / CHCl₃ / 1 h / Ambient temperature

With 1,8-diazabicyclo[2.2.2.]octane; Vilsmeier reagent; mercury dichloride; mercury(II) oxide; Wilkinson's catalyst; In chloroform;
DOI:10.1016/0008-6215(93)84087-M

Reference yield:

: 152157-72-7
allyl 3,6-di-O-benzyl-2-deoxy-4-O-methyl-2-phthalimido-β-D-glucopyranoside

: 3,6-di-O-benzyl-2-deoxy-4-O-methyl-2-phthalimido-α,β-D-glucopyranose

Guidance literature:: With 1,8-diazabicyclo[2.2.2.]octane; mercury dichloride; mercury(II) oxide; Wilkinson's catalyst; Yield given. Multistep reaction; 1.) EtOH, benzene, H₂O, reflux, 30 h, 2.) acetone, H₂O, 2 h;
DOI:10.1016/0008-6215(93)84087-M