1-(Me₃SiCC)-1'-((C₅Me₅)(bis(diphenylphosphino)ethane)RuCC)((C₅H₄)2Fe)

Base Information

• Chemical Name: 1-(Me₃SiCC)-1'-((C₅Me₅)(bis(diphenylphosphino)ethane)RuCC)((C₅H₄)2Fe)
• CAS No.: 869370-70-7
• Molecular Formula: C₅₃H₅₆FeP₂RuSi
• Molecular Weight: 939.978

Synonyms:1-(Me₃SiCC)-1'-((C₅Me₅)(bis(diphenylphosphino)ethane)RuCC)((C₅H₄)2Fe)

Chemical Property of 1-(Me₃SiCC)-1'-((C₅Me₅)(bis(diphenylphosphino)ethane)RuCC)((C₅H₄)2Fe)

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Technology Process of 1-(Me₃SiCC)-1'-((C₅Me₅)(bis(diphenylphosphino)ethane)RuCC)((C₅H₄)2Fe)

There total 2 articles about 1-(Me₃SiCC)-1'-((C₅Me₅)(bis(diphenylphosphino)ethane)RuCC)((C₅H₄)2Fe) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 46.0%

pentamethylcyclopentadienyl(1,2-bis(diphenylphosphino)ethane)chlororuthenium(II) + 1,1’-bis(trimethylsilylethynyl)ferrocene → 1-(Me3SiCC)-1'-((C5Me5)(bis(diphenylphosphino)ethane)RuCC)((C5H4)2Fe) (869370-70-7) + [(ruthenium(II)(η5-pentamethylcyclopentadienyl)(1,2-bis(diphenylphosphino)ethane)C2)2(ferrocenyl)]

Guidance literature:

With potassium fluoride; In methanol; under Ar atm. mixt. Fe complex, 1,1'-(Me3SiCC)2Fc' and KF in MeOH was heated at reflux for 16 h; react. mixt. was cooled to room temp., ppt. was filtered, washed with MeOH, dried, dissolved in benzene, filtered and diluted with hexane, storing in freezer overnight - 1,1'-(Cp*(dppe)RuCC)2Fc', filtrate - 1-(Me3SiCC)-1'-(Cp*(dppe)RuCC)Fc'; elem. anal.;

DOI:10.1021/om050483l

Reference yield: 46.0%

pentamethylcyclopentadienyl(1,2-bis(diphenylphosphino)ethane)chlororuthenium(II) + 1,1’-bis(trimethylsilylethynyl)ferrocene → 1-(Me3SiCC)-1'-((C5Me5)(bis(diphenylphosphino)ethane)RuCC)((C5H4)2Fe) (869370-70-7)

Guidance literature:

With KF; In not given; according to Bruce M. I., et al., Organometallics, 2005, 24, 5241; Fe complex and Ru complex (1 equiv.) were reacted in presence of KF;

DOI:10.1016/j.jorganchem.2006.11.035

Reference yield: 84.0%

1-(Me3SiCC)-1'-((C5Me5)(bis(diphenylphosphino)ethane)RuCC)((C5H4)2Fe) (869370-70-7) → 1-(HCC)-1'-((C5Me5)(bis(diphenylphosphino)ethane)RuCC)((C5H4)2Fe) (934705-66-5)

Guidance literature:

With NH₄F; In tetrahydrofuran; (N2); soln. of NH4F in THF was added to soln. of Ru-Fe complex in THF; mixt. was stirred at room temp. for 16 h; solvent removed (vac.); extd. (Et2O); filtered through alumina; evapd.; elem. anal.;

DOI:10.1016/j.jorganchem.2006.11.035

Downstream raw materials:

1-(HCC)-1'-((C₅Me₅)(bis(diphenylphosphino)ethane)RuCC)((C₅H₄)2Fe)

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