(2-Methyl-1,4-dioxobutyl)methyldiphenylsilane

Base Information

Chemical Name:(2-Methyl-1,4-dioxobutyl)methyldiphenylsilane
CAS No.:162317-73-9
Molecular Formula:C₁₈H₂₀O₂Si
Molecular Weight:296.441
Hs Code.:

Synonyms:(2-Methyl-1,4-dioxobutyl)methyldiphenylsilane

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Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of (2-Methyl-1,4-dioxobutyl)methyldiphenylsilane

Chemical Property:

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Technology Process of (2-Methyl-1,4-dioxobutyl)methyldiphenylsilane

There total 4 articles about (2-Methyl-1,4-dioxobutyl)methyldiphenylsilane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 61.0%

: 162318-07-2
<2-(1-Methyl-3-oxopropyl)-1,3-dithian-2-yl>methyldiphenylsilane

: 162317-73-9
(2-Methyl-1,4-dioxobutyl)methyldiphenylsilane

Guidance literature:: With 2,3,5-trimethyl-pyridine; water; mercury dichloride; In acetone; Ambient temperature;
DOI:10.1021/jo00106a025

Reference yield:

: 144-79-6
chloromethyldiphenylsilane

: 162317-73-9
(2-Methyl-1,4-dioxobutyl)methyldiphenylsilane

Guidance literature:: Multi-step reaction with 4 steps

1: 90 percent / n-BuLi / tetrahydrofuran; hexane / 1.) -25 deg C, 2.5 h, 2.) -40 deg C to r.t., overnight

2: 31 percent / n-BuLi / 1.) THF, hexane, -25 deg C, 2.5 h, 2.) HMPA, -78 deg C, 4 h

3: 95 percent / 3 N aq. HCl / tetrahydrofuran / Ambient temperature

4: 61 percent / H₂O, HgCl₂, collidine / acetone / Ambient temperature

With 2,3,5-trimethyl-pyridine; hydrogenchloride; n-butyllithium; water; mercury dichloride; In tetrahydrofuran; hexane; acetone;
DOI:10.1021/jo00106a025

Reference yield:

: 135746-47-3
2-methyldiphenylsilyl-1,3-dithiane

: 162317-73-9
(2-Methyl-1,4-dioxobutyl)methyldiphenylsilane

Guidance literature:: Multi-step reaction with 3 steps

1: 31 percent / n-BuLi / 1.) THF, hexane, -25 deg C, 2.5 h, 2.) HMPA, -78 deg C, 4 h

2: 95 percent / 3 N aq. HCl / tetrahydrofuran / Ambient temperature

3: 61 percent / H₂O, HgCl₂, collidine / acetone / Ambient temperature

With 2,3,5-trimethyl-pyridine; hydrogenchloride; n-butyllithium; water; mercury dichloride; In tetrahydrofuran; acetone;
DOI:10.1021/jo00106a025