allyl(3,3,4,4,5,5,6,6,7,7,8,8,9,9,10,10,10-heptadecafluorodecyl)dimethylsilane

Base Information

• Chemical Name: allyl(3,3,4,4,5,5,6,6,7,7,8,8,9,9,10,10,10-heptadecafluorodecyl)dimethylsilane
• CAS No.: 1057672-67-9
• Molecular Formula: C₁₅H₁₅F₁₇Si
• Molecular Weight: 546.342
• Mol file: 1057672-67-9.mol

Synonyms:allyl(3,3,4,4,5,5,6,6,7,7,8,8,9,9,10,10,10-heptadecafluorodecyl)dimethylsilane

Chemical Property of allyl(3,3,4,4,5,5,6,6,7,7,8,8,9,9,10,10,10-heptadecafluorodecyl)dimethylsilane

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of allyl(3,3,4,4,5,5,6,6,7,7,8,8,9,9,10,10,10-heptadecafluorodecyl)dimethylsilane

There total 1 articles about allyl(3,3,4,4,5,5,6,6,7,7,8,8,9,9,10,10,10-heptadecafluorodecyl)dimethylsilane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 79.0%

chloro(3,3,4,4,5,5,6,6,7,7,8,8,9,9,10,10,10-heptadecafluorodecyl)dimethylsilane (74612-30-9) + allylmagnesium bromide (1730-25-2) → allyl(3,3,4,4,5,5,6,6,7,7,8,8,9,9,10,10,10-heptadecafluorodecyl)dimethylsilane (1057672-67-9) + 1,3-bis(heptadecafluoro-1,1,2,2-tetrahydrodecyl)tetramethyldisiloxane

Guidance literature:

In tetrahydrofuran; diethyl ether; at 0 - 20 ℃; Inert atmosphere;

DOI:10.1039/b804484h

Reference yield: 40.0%

allyl(3,3,4,4,5,5,6,6,7,7,8,8,9,9,10,10,10-heptadecafluorodecyl)dimethylsilane (1057672-67-9) + benzoic acid hex-5-enyl ester (41795-26-0) → 7-(dimethyl-(3,3,4,4,5,5,6,6,7,7,8,8,9,9,10,10,10-heptadecafluorodecyl)silyl)hept-5-enyl benzoate (1057672-73-7)

Guidance literature:

With (1,3-dimesityl-4,5-dihydroimidazol-2-ylidene)(PCy₃)Cl₂Ru=CHPh; p-benzoquinone; In dichloromethane; for 12h; Reflux; Inert atmosphere;

DOI:10.1039/b804484h

Reference yield:

allyl(3,3,4,4,5,5,6,6,7,7,8,8,9,9,10,10,10-heptadecafluorodecyl)dimethylsilane (1057672-67-9) + vinyl benzoate (583-04-0) → (Z)-4-((3,3,4,4,5,5,6,6,7,7,8,8,9,9,10,10,10-heptadecafluorodecyl)dimethylsilyl)but-2-enyl benzoate + (E)-4-((3,3,4,4,5,5,6,6,7,7,8,8,9,9,10,10,10-heptadecafluorodecyl)dimethylsilyl)but-2-enyl benzoate (1057672-75-9)

Guidance literature:

With Hoveyda-Grubbs II catalyst; p-benzoquinone; In dichloromethane; for 12h; optical yield given as %de; Reflux; Inert atmosphere;

DOI:10.1039/b804484h

upstream raw materials:

chloro(3,3,4,4,5,5,6,6,7,7,8,8,9,9,10,10,10-heptadecafluorodecyl)dimethylsilane

allylmagnesium bromide

Downstream raw materials:

(E)-4-((3,3,4,4,5,5,6,6,7,7,8,8,9,9,10,10,10-heptadecafluorodecyl)dimethylsilyl)but-2-enyl benzoate

7-(dimethyl-(3,3,4,4,5,5,6,6,7,7,8,8,9,9,10,10,10-heptadecafluorodecyl)silyl)hept-5-enyl benzoate