Technology Process of 5,6-carboranylene-1,1,4,4-tetraethyl-2-phenyl-1,4-disilacyclohex-2-ene
There total 1 articles about 5,6-carboranylene-1,1,4,4-tetraethyl-2-phenyl-1,4-disilacyclohex-2-ene which
guide to synthetic route it.
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synthetic route:
- Guidance literature:
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tetrakis(triphenylphosphine) palladium(0);
In
toluene;
mixt. 3,4-carboranylene-1,1,2,2-tetraethyl-1,2-disilacyclobut-3-ene and phenylacetylene in the presence of Pd(PPh3)4 in toluene was refluxed for24 h; solvent was removed in vacuo, residue was chromed. (benzene/hexane 1:2) and crystd. from hexane at -10°C; elem. anal.;
DOI:10.1021/om010535g