(4R,6R)-6-(benzyloxy)-4-(2,6-dichlorobenzyloxy)-8-methylnon-1-ene

Base Information

• Chemical Name: (4R,6R)-6-(benzyloxy)-4-(2,6-dichlorobenzyloxy)-8-methylnon-1-ene
• CAS No.: 1095268-29-3
• Molecular Formula: C₂₄H₃₀Cl₂O₂
• Molecular Weight: 421.407
• Mol file: 1095268-29-3.mol

Synonyms:(4R,6R)-6-(benzyloxy)-4-(2,6-dichlorobenzyloxy)-8-methylnon-1-ene

Chemical Property of (4R,6R)-6-(benzyloxy)-4-(2,6-dichlorobenzyloxy)-8-methylnon-1-ene

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of (4R,6R)-6-(benzyloxy)-4-(2,6-dichlorobenzyloxy)-8-methylnon-1-ene

There total 1 articles about (4R,6R)-6-(benzyloxy)-4-(2,6-dichlorobenzyloxy)-8-methylnon-1-ene which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 97.0%

(4R,6R)-6-(benzyloxy)-8-methylnon-1-en-4-ol (1095268-26-0) + 2,6-Dichlorobenzyl bromide (20443-98-5) → (4R,6R)-6-(benzyloxy)-4-(2,6-dichlorobenzyloxy)-8-methylnon-1-ene (1095268-29-3)

Guidance literature:

(4R,6R)-6-(benzyloxy)-8-methylnon-1-en-4-ol; With sodium hydride; In N,N-dimethyl-formamide; mineral oil; at 0 ℃; for 0.333333h; Inert atmosphere;

2,6-Dichlorobenzyl bromide; With tetra-(n-butyl)ammonium iodide; In N,N-dimethyl-formamide; mineral oil; at 0 - 20 ℃; Inert atmosphere;

DOI:10.1016/j.tet.2008.09.038

Reference yield: 90.0%

(4R,6R)-6-(benzyloxy)-4-(2,6-dichlorobenzyloxy)-8-methylnon-1-ene (1095268-29-3) → (4R,6R)-6-(benzyloxy)-4-(2,6-dichlorobenzyloxy)-8-methylnonan-1-ol (1095268-32-8)

Guidance literature:

(4R,6R)-6-(benzyloxy)-4-(2,6-dichlorobenzyloxy)-8-methylnon-1-ene; With 9-bora-bicyclo[3.3.1]nonane; In tetrahydrofuran; at 0 - 20 ℃; Inert atmosphere;

With dihydrogen peroxide; sodium acetate; In tetrahydrofuran; ethanol; water; at 0 - 20 ℃; for 6h;

DOI:10.1016/j.tet.2008.09.038

Reference yield:

(4R,6R)-6-(benzyloxy)-4-(2,6-dichlorobenzyloxy)-8-methylnon-1-ene (1095268-29-3) + 9-bora-bicyclo[3.3.1]nonane (280-64-8) → C32H45BCl2O2

Guidance literature:

In tetrahydrofuran; at 0 - 20 ℃;

DOI:10.1055/s-0028-1083185

upstream raw materials:

(4R,6R)-6-(benzyloxy)-8-methylnon-1-en-4-ol

2,6-Dichlorobenzyl bromide

Downstream raw materials:

(4R,6R)-6-(benzyloxy)-4-(2,6-dichlorobenzyloxy)-8-methylnonan-1-ol