azido(tetraphenylporphyrinato)iron(III)

Base Information

• Chemical Name: azido(tetraphenylporphyrinato)iron(III)
• CAS No.: 51455-98-2
• Molecular Formula: C₄₄H₂₈FeN₇
• Molecular Weight: 710.6
• Mol file: 51455-98-2.mol

Synonyms:azido(tetraphenylporphyrinato)iron(III)

Chemical Property of azido(tetraphenylporphyrinato)iron(III)

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of azido(tetraphenylporphyrinato)iron(III)

There total 3 articles about azido(tetraphenylporphyrinato)iron(III) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 92.0%

μ-oxo-bis[α,β,γ,δ-tetraphenylporphinatoiron] (12582-61-5) → azido(tetraphenylporphyrinato)iron(III) (51455-98-2)

Guidance literature:

With sodium azide; sulfuric acid; In water; benzene; addn. of aq. NaN3 to porphinate in C6H6 (stirring); addn. of excess concd. H2SO4; stirring for 1.5 h; washing of org. layer with water; drying over MgSO4; filtration; evapn.; drying (vac., room temp., 24 h); elem. anal.;

Reference yield: 58.0%

5,10,15,20-tetraphenyl porphyrinato iron hydroxide (25482-26-2) → azido(tetraphenylporphyrinato)iron(III) (51455-98-2)

Guidance literature:

With sodium azide; In water; toluene; mixing soln. of NaN3 in water and Fe-complex in toluene, stirring vigorously overnight; removal of toluene layer by pipette, evapn. (vac., slight warming), recrystn. (CH2Cl2);

DOI:10.1039/DT9920001669

Reference yield:

sodium azide + meso-tetraphenylporphyrin iron(III) chloride (16456-81-8,170645-84-8) → azido(tetraphenylporphyrinato)iron(III) (51455-98-2)

Guidance literature:

prepared according to the method by D. A. Summerville and I. A. Cohen, J. Am. Chem. Soc. 1976, 98, 1747; elem. anal.;

DOI:10.1016/S0277-5387(00)80159-X

upstream raw materials:

μ-oxo-bis[α,β,γ,δ-tetraphenylporphinatoiron]

meso-tetraphenylporphyrin iron(III) chloride

5,10,15,20-tetraphenyl porphyrinato iron hydroxide

Downstream raw materials:

Fe(C₄₄H₂₈N₄)(C₄H₆N₂)2⁽¹⁺⁾*N₃^(1-)=(Fe(C₄₄H₂₈N₄)(C₄H₆N₂)2)N₃

5,10,15,20-tetraphenyl porphyrin iron

azide radical

nitridoiron(V)tetraphenylporphyrin