[closo-3,3-(triphenylphosphine)2-3-NO₃-3,1,2-RhC₂B₉H₁₁]

Base Information

Chemical Name:[closo-3,3-(triphenylphosphine)2-3-NO₃-3,1,2-RhC₂B₉H₁₁]
CAS No.:72930-70-2
Molecular Formula:C₃₈H₄₁B₉NO₃P₂Rh
Molecular Weight:821.9
Hs Code.:

[closo-3,3-(triphenylphosphine)2-3-NO<sub>3</sub>-3,1,2-RhC<sub>2</sub>B<sub>9</sub>H<sub>11</sub>]

Synonyms:[closo-3,3-(triphenylphosphine)2-3-NO₃-3,1,2-RhC₂B₉H₁₁]

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Chemical Property of [closo-3,3-(triphenylphosphine)2-3-NO₃-3,1,2-RhC₂B₉H₁₁]

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Technology Process of [closo-3,3-(triphenylphosphine)2-3-NO₃-3,1,2-RhC₂B₉H₁₁]

There total 2 articles about [closo-3,3-(triphenylphosphine)2-3-NO₃-3,1,2-RhC₂B₉H₁₁] which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 81.0%

: 82807-97-4
[closo-3-triphenylphosphine-3,3-nitrato-3,1,2-RhC₂B₉H₁₁]

: 72930-70-2
[closo-3,3-(triphenylphosphine)2-3-NO₃-3,1,2-RhC₂B₉H₁₁]

Guidance literature:: With PPh₃; In diethyl ether; under Ar, PPh3 added to stirred soln. of Rh complex in diethyl ether atroom temp., mixt. stirred for 15 min; heptane added, diethyl ether removed in vac., ppt. collected in air, washed with heptane, dried by suction and in vac., elem. anal.;

Reference yield: 77.0%

: 82808-02-4
[closo-3-triphenylphosphine-3-CO-3-NO₃-3,1,2-RhC₂B₉H₁₁]

: 72930-70-2
[closo-3,3-(triphenylphosphine)2-3-NO₃-3,1,2-RhC₂B₉H₁₁]

Guidance literature:: With PPh₃; In diethyl ether; under Ar, solid mixt. of Rh complex and PPh3 dissolved in diethyl ether, soln. stirred at room temp. for 30 min; heptane added, diethyl ether removed in vac., concd., ppt. filtered offin air, washed with pentane, dried by suction;

Reference yield: 79.0%

: 72930-70-2
[closo-3,3-(triphenylphosphine)2-3-NO₃-3,1,2-RhC₂B₉H₁₁]

: 53687-46-0
closo-3,3-(PPh₃)2-3-H-3,1,2-RhC₂B₉H₁₁

Guidance literature:: With H₂; In tetrahydrofuran; under Ar, H2 (1 atm) bubbled through stirred soln. of Rh complex in THFat room temp., stirred for 10 min; abs. ethanol added, evapd. in vac., ppt. collected in air, washed with ethanol and diethyl ether, dried by suction;