Methyl O-(2,3,6-tri-O-benzyl-α-D-glucopyranosyl)-(1->4)-O-(tert-butyl 2,3-di-O-benzyl-β-D-glucopyranoside)uronate

Base Information

Chemical Name:Methyl O-(2,3,6-tri-O-benzyl-α-D-glucopyranosyl)-(1->4)-O-(tert-butyl 2,3-di-O-benzyl-β-D-glucopyranoside)uronate
CAS No.:171356-82-4
Molecular Formula:C₅₂H₆₀O₁₂
Molecular Weight:877.041
Hs Code.:

Synonyms:Methyl O-(2,3,6-tri-O-benzyl-α-D-glucopyranosyl)-(1->4)-O-(tert-butyl 2,3-di-O-benzyl-β-D-glucopyranoside)uronate

Suppliers and Price of Methyl O-(2,3,6-tri-O-benzyl-α-D-glucopyranosyl)-(1->4)-O-(tert-butyl 2,3-di-O-benzyl-β-D-glucopyranoside)uronate

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 0 raw suppliers

Chemical Property of Methyl O-(2,3,6-tri-O-benzyl-α-D-glucopyranosyl)-(1->4)-O-(tert-butyl 2,3-di-O-benzyl-β-D-glucopyranoside)uronate

Chemical Property:

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:

Useful:

Technology Process of Methyl O-(2,3,6-tri-O-benzyl-α-D-glucopyranosyl)-(1->4)-O-(tert-butyl 2,3-di-O-benzyl-β-D-glucopyranoside)uronate

There total 4 articles about Methyl O-(2,3,6-tri-O-benzyl-α-D-glucopyranosyl)-(1->4)-O-(tert-butyl 2,3-di-O-benzyl-β-D-glucopyranoside)uronate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 87.0%

: 171356-80-2
Methyl O-(2,3-di-O-benzyl-4,6-O-benzylidene-α-D-glucopyranosyl)-(1->4)-O-(tert-butyl 2,3-di-O-benzyl-β-D-glucopyranoside)uronate

: 171356-82-4
Methyl O-(2,3,6-tri-O-benzyl-α-D-glucopyranosyl)-(1->4)-O-(tert-butyl 2,3-di-O-benzyl-β-D-glucopyranoside)uronate

Guidance literature:: With hydrogenchloride; 3 A molecular sieve; sodium cyanoborohydride; In tetrahydrofuran; diethyl ether; for 0.5h; Ambient temperature;

Reference yield:

: (2R,4aR,6R,7R,8R,8aS)-6-[(2R,3S,4R,5R,6R)-2-(tert-Butyl-dimethyl-silanyloxymethyl)-4,5-dihydroxy-6-methoxy-tetrahydro-pyran-3-yloxy]-2-phenyl-hexahydro-pyrano[3,2-d][1,3]dioxine-7,8-diol

: 171356-82-4
Methyl O-(2,3,6-tri-O-benzyl-α-D-glucopyranosyl)-(1->4)-O-(tert-butyl 2,3-di-O-benzyl-β-D-glucopyranoside)uronate

Guidance literature:: Multi-step reaction with 4 steps

1: NaH / dimethylformamide / 4 h / Ambient temperature

2: 91 percent / Bu₄NF / tetrahydrofuran / 2 h / Ambient temperature

3: 84 percent / PDC, Ac₂O / CH₂Cl₂ / 4 h / Ambient temperature

4: 87 percent / NaCNBH₃, HCl, 3 Angstroem molecular sieves / diethyl ether; tetrahydrofuran / 0.5 h / Ambient temperature

With hydrogenchloride; dipyridinium dichromate; 3 A molecular sieve; tetrabutyl ammonium fluoride; acetic anhydride; sodium hydride; sodium cyanoborohydride; In tetrahydrofuran; diethyl ether; dichloromethane; N,N-dimethyl-formamide;

Reference yield:

: 171356-78-8
Methyl O-(2,3-di-O-benzyl-4,6-O-benzylidene-α-D-glucopyranosyl)-(1->4)-2,3-di-O-benzyl-6-O-tert-butyldimethylsilyl-β-D-glucopyranoside

: 171356-82-4
Methyl O-(2,3,6-tri-O-benzyl-α-D-glucopyranosyl)-(1->4)-O-(tert-butyl 2,3-di-O-benzyl-β-D-glucopyranoside)uronate

Guidance literature:: Multi-step reaction with 3 steps

1: 91 percent / Bu₄NF / tetrahydrofuran / 2 h / Ambient temperature

2: 84 percent / PDC, Ac₂O / CH₂Cl₂ / 4 h / Ambient temperature

3: 87 percent / NaCNBH₃, HCl, 3 Angstroem molecular sieves / diethyl ether; tetrahydrofuran / 0.5 h / Ambient temperature

With hydrogenchloride; dipyridinium dichromate; 3 A molecular sieve; tetrabutyl ammonium fluoride; acetic anhydride; sodium cyanoborohydride; In tetrahydrofuran; diethyl ether; dichloromethane;