[(η(5)-C5H4Me)2Fe][B(C6H5)4]

Base Information

Chemical Name:[(η(5)-C5H4Me)2Fe][B(C6H5)4]
CAS No.:123264-20-0
Molecular Formula:C₁₂H₁₄Fe*C₂₄H₂₀B
Molecular Weight:533.324
Hs Code.:

Synonyms:[(η(5)-C5H4Me)2Fe][B(C6H5)4]

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Chemical Property of [(η(5)-C5H4Me)2Fe][B(C6H5)4]

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Technology Process of [(η(5)-C5H4Me)2Fe][B(C6H5)4]

There total 1 articles about [(η(5)-C5H4Me)2Fe][B(C6H5)4] which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 91.9%

: 1291-47-0
1,1'-dimethylferrocene

: 143-66-8
sodium tetraphenyl borate

: 123264-20-0
[(η(5)-C5H4Me)2Fe][B(C6H5)4]

Guidance literature:: With H₂SO₄; In water; Cp'2Fe, concd. H2SO4: stirring at 25°C, 40 min, blue-green solution; adding to ice water, stirring, filtration, deep blue solution; adding to NaBPh4/H2O; filtration; washing (H2O);
DOI:10.1021/om00114a026

Reference yield: 86.0%

: 123264-20-0
[(η(5)-C5H4Me)2Fe][B(C6H5)4]

: Cp*Zr(CH₂Ph)3

: (C₅(CH₃)5)Zr(CH₂C₆H₅)2(C₄H₈O)⁽¹⁺⁾*B(C₆H₅)4^(1-)={(C₅(CH₃)5)Zr(CH₂C₆H₅)2(C₄H₈O)}{B(C₆H₅)4}

Guidance literature:: In tetrahydrofuran; byproducts: (C5H4Me)2Fe, PhCH2CH2Ph; vac.; THF addn. to mixt. of educts (-78°C), stirring (warming to 0°C), stirring (0°C, 1 h); removal of solvent (vac.), washing (toluene), drying (vac., 24 h), recrystn. (THF/hexane or /THF/Et2O);
DOI:10.1021/om00159a028

Reference yield: 76.0%

: 123264-20-0
[(η(5)-C5H4Me)2Fe][B(C6H5)4]

: rac-(ethylenebis(tetrahydroindenyl))Zr(CH₂Ph)2

: {(ethylenebis(tetrahydroindenyl))Zr(CH₂Ph)(tetrahydrofuran)}{BPh₄}

Guidance literature:: In tetrahydrofuran; byproducts: bibenzyl; inert atmosphere or vac., dry solvents, addn. of THF at -78°C to Zr-compd. and ((C5H4CH3)2Fe)BPh4 by vac. transfer, warming soln. to room temperature, stirring (30 min); concn. vol. to 25 ml, filtration, redn. of vol., addn. of toluene at -78°C, removal of solvent in vac., washing (toluene), drying, addn. of THF, warming to room temperature with stirring, filtration, washing (THF), drying in vac.; elem. anal.;
DOI:10.1021/om00119a028