(R)SCHROCK-HOVEYDA CATALYST

Base Information

Chemical Name:(R)SCHROCK-HOVEYDA CATALYST
CAS No.:329735-77-5
Molecular Formula:C₄₆H₆₁MoNO₂
Molecular Weight:755.936
Hs Code.:

Synonyms:2,6-DIISOPROPYLPHENYLIMIDONEOPHYLIDENE[RACEMIC-BIPHEN]MOLYBDENIUM(VI);2,6-DIISOPROPYLPHENYLIMIDO-NEOPHYLIDENE[RACEMIC-BIPHEN]MOLYBDENUM(VI);2,6-DIISOPROPYLPHENYLIMIDONEOPHYLIDENE[(R)-(+)-BIPHEN]MOLYBDENIUM(VI);2,6-DIISOPROPYLPHENYLIMIDONEOPHYLIDENE [(R)-(+)-BIPHEN]MOLYBDENUM(VI);2,6-DIISOPROPYLPHENYLIMIDONEOPHYLIDENE[(S)-(-)BIPHEN]MOLYBDENIUM(VI);2,6-DIISOPROPYLPHENYLIMIDO-NEOPHYLIDENE[(S)-(-)-BIPHEN]MOLYBDENUM(VI);(S)-SCHROCK-HOVEYDA CATALYST;(R)SCHROCK-HOVEYDA CATALYST

Suppliers and Price of (R)SCHROCK-HOVEYDA CATALYST

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Strem Chemicals
2,6-Diisopropylphenylimidoneophylidene[(R)-(+)-BIPHEN]molybdenum(VI), min. 97% (R) SCHROCK-HOVEYDA CATALYST
100mg
$ 303.00

Strem Chemicals
2,6-Diisopropylphenylimidoneophylidene[(R)-(+)-BIPHEN]molybdenum(VI), min. 97% (R) SCHROCK-HOVEYDA CATALYST
25mg
$ 101.00

American Custom Chemicals Corporation
2,6-DIISOPROPYLPHENYLIMIDONEOPHYLIDENE [(R)-(+)-BIPHEN]MOLYBDENUM (VI) 95.00%
100MG
$ 899.25

Total 8 raw suppliers

Chemical Property of (R)SCHROCK-HOVEYDA CATALYST

Chemical Property:

PSA：30.82000
LogP:13.48190
Storage Temp.:2-8°C
Sensitive.:air sensitive, moisture sensitiv

Purity/Quality:

99% ^*data from raw suppliers

2,6-Diisopropylphenylimidoneophylidene[(R)-(+)-BIPHEN]molybdenum(VI), min. 97% (R) SCHROCK-HOVEYDA CATALYST ^*data from reagent suppliers

Safty Information:

Pictogram(s):
Hazard Codes:
Statements: 20/21/22-36/37/38
Safety Statements: 26-36/37/39

MSDS Files:: SDS file from LookChem

Useful:

Technology Process of (R)SCHROCK-HOVEYDA CATALYST

There total 5 articles about (R)SCHROCK-HOVEYDA CATALYST which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 78.0%

: Mo(CHCMe₂Ph)(N-2,6-diisopropylPh)(OTf)2*dme

: 329735-68-4,101203-31-0,205927-03-3
(S)-3,3'-di-tert-butyl-5,5',6,6'-tetramethyl-1,1'-biphenyl-2,2'-diol

: 205815-80-1,329735-77-5,300344-02-9
[molybdenum(diisopropylphenylimido)(CHC(CH₃)2C₆H₅)(OC₆H(CH₃)2C(CH₃)3)2]

Guidance literature:: With KH; In tetrahydrofuran; under N2; KH was added to a stirred soln. of the ligand in THF, after 18 h the complex was added, the soln. was stirred for 3 h; the soln. was concd. in vac., residue was extd. with C6H6, suspn. was filtered through Celite, solvent was removed in vac., (CH3CH2)2O was added, soln. was concd. in vac., soln. was kept at 20°C for 2 h, fourcrops were collected;
DOI:10.1021/om000336h

Reference yield: 72.0%

: Mo(CHCMe₂Ph)(N-2,6-diisopropylPh)(OTf)2*dme

: 101203-31-0
3,3'-di-tert-butyl-5,5',6,6'-tetramethylbiphenyl-2,2'-diol

: 205815-80-1,300344-02-9,329735-77-5
(2,6-diisopropylphenylimide){3,3′-di(t-butyl)-5,5′,6,6′-tetramethyl-2,2′-biphenoxy}neophylidenemolybdenum(VI)

Guidance literature:: With KH; In tetrahydrofuran; under N2; KH was added to a stirred soln. of the ligand in THF, after 3 h the complex was added, the soln. was stirred for 2 h; soln. was concd. in vac., residue was extd. with C6H6, suspn. was filtered through Celite, solvent was removed in vac., (CH3CH2)2O was added, soln. was concd., soln. was decanted, washed with cold (CH3CH2)2O, dried in vac.; elem. anal.;
DOI:10.1021/om000336h

Reference yield: 49.0%

: Mo(NAr)(CHCMe₂Ph)(OTf)2(dimethoxyethane)

: 101203-31-0
3,3'-di-tert-butyl-5,5',6,6'-tetramethylbiphenyl-2,2'-diol

: 205815-80-1,300344-02-9,329735-77-5
(2,6-diisopropylphenylimide){3,3′-di(t-butyl)-5,5′,6,6′-tetramethyl-2,2′-biphenoxy}neophylidenemolybdenum(VI)

Guidance literature:: 3,3'-di-tert-butyl-5,5',6,6'-tetramethylbiphenyl-2,2'-diol; With potassium hydride; In tetrahydrofuran; at -30 ℃; for 24h;

Mo(NAr)(CHCMe₂Ph)(OTf)2(dimethoxyethane); In tetrahydrofuran; at -30 - 20 ℃;