Technology Process of [Fe(CO)4(CNCH2C6H5)]
There total 1 articles about [Fe(CO)4(CNCH2C6H5)] which
guide to synthetic route it.
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synthetic route:
- Guidance literature:
-
With
n-butyllithium; Chloro-oxo-acetic acid;
In
tetrahydrofuran;
under Ar; nBuLi added to soln. of amine in THF at -80°C, after 30min mixt. warmed to -10°C, soln. of Fe(CO)5 in THF added dropwis e, after 30 min mixt. cooled to -30°C, oxalylchloride added, stirred for 1 h; evapd. to dryness, amine sepd. by extracting residue with hexane at -40°C, residue extd. with hexane at 0°C, crystn. after 1 d at -30°C; elem. anal.;
DOI:10.1016/S0020-1693(02)01553-0
- Guidance literature:
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cobalt(II) chloride dihydrate;
In
benzene;
byproducts: CO; isonitrile added to soln. of Fe complex and Co salt, refluxed for 10 min, under Ar; cooled, chromd. (silica, benzene), evapd.; elem. anal.;
- Guidance literature:
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palladium(II) oxide;
In
benzene;
byproducts: CO; The mixt. of complex and catalyst in benzene was heated to reflux and then t-BuNC was added; 2 min; influence of different catalysts on this reaction;; not sepd., detected by IR-spectra;;
DOI:10.1016/0022-328X(87)87126-7
