1-benzyloxy-3-methylhept-2(Z)-ene

Base Information

Chemical Name:1-benzyloxy-3-methylhept-2(Z)-ene
CAS No.:251639-68-6
Molecular Formula:C₁₅H₂₂O
Molecular Weight:218.339
Hs Code.:

Synonyms:1-benzyloxy-3-methylhept-2(Z)-ene

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Chemical Property of 1-benzyloxy-3-methylhept-2(Z)-ene

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Technology Process of 1-benzyloxy-3-methylhept-2(Z)-ene

There total 4 articles about 1-benzyloxy-3-methylhept-2(Z)-ene which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 65.0%

: 251639-67-5
(E)-2-(2-benzyloxyethylidene)hexan-1-ol

: 251639-68-6
1-benzyloxy-3-methylhept-2(Z)-ene

Guidance literature:: (E)-2-(2-benzyloxyethylidene)hexan-1-ol; With sulfur trioxide pyridine complex; In tetrahydrofuran; at 0 ℃; for 2h;

With lithium aluminium tetrahydride; In tetrahydrofuran; at -30 - 20 ℃; for 20.5h;
DOI:10.1007/BF02495308

Reference yield:

: 56951-64-5
N-tert-butylhexan-1-imine

: 251639-68-6
1-benzyloxy-3-methylhept-2(Z)-ene

Guidance literature:: Multi-step reaction with 4 steps

1.1: lithium diisopropylamide / tetrahydrofuran; hexane / 0.5 h / 0 °C

1.2: 80 percent / hexane; tetrahydrofuran / 2.5 h / -70 °C

2.1: lithium diisopropylamide / tetrahydrofuran; hexane / 0.67 h / -10 °C

2.2: 55 percent / tetrahydrofuran; hexane / 2.5 h / -70 °C

3.1: 92 percent / NaBH₄ / ethanol / 0.33 h / 20 °C

4.1: Py*SO₃ / tetrahydrofuran / 2 h / 0 °C

4.2: 65 percent / LiAlH₄ / tetrahydrofuran / 20.5 h / -30 - 20 °C

With sodium tetrahydroborate; sulfur trioxide pyridine complex; lithium diisopropyl amide; In tetrahydrofuran; ethanol; hexane; 1.1: Metallation / 1.2: Substitution / 2.1: Metallation / 2.2: Condensation / 3.1: Reduction / 4.1: Substitution / 4.2: Reduction;
DOI:10.1007/BF02495308

Reference yield:

: 66-25-1
hexanal

: 251639-68-6
1-benzyloxy-3-methylhept-2(Z)-ene

Guidance literature:: Multi-step reaction with 5 steps

1.1: 77.6 percent / diethyl ether / 2 h / 0 °C

2.1: lithium diisopropylamide / tetrahydrofuran; hexane / 0.5 h / 0 °C

2.2: 80 percent / hexane; tetrahydrofuran / 2.5 h / -70 °C

3.1: lithium diisopropylamide / tetrahydrofuran; hexane / 0.67 h / -10 °C

3.2: 55 percent / tetrahydrofuran; hexane / 2.5 h / -70 °C

4.1: 92 percent / NaBH₄ / ethanol / 0.33 h / 20 °C

5.1: Py*SO₃ / tetrahydrofuran / 2 h / 0 °C

5.2: 65 percent / LiAlH₄ / tetrahydrofuran / 20.5 h / -30 - 20 °C

With sodium tetrahydroborate; sulfur trioxide pyridine complex; lithium diisopropyl amide; In tetrahydrofuran; diethyl ether; ethanol; hexane; 1.1: Condensation / 2.1: Metallation / 2.2: Substitution / 3.1: Metallation / 3.2: Condensation / 4.1: Reduction / 5.1: Substitution / 5.2: Reduction;
DOI:10.1007/BF02495308