Rhenium(O)I(PhCCPh)2

Base Information

Chemical Name:Rhenium(O)I(PhCCPh)2
CAS No.:123170-29-6
Molecular Formula:C₂₈H₂₀IORe
Molecular Weight:685.578
Hs Code.:

Synonyms:Rhenium(O)I(PhCCPh)2

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Chemical Property of Rhenium(O)I(PhCCPh)2

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Technology Process of Rhenium(O)I(PhCCPh)2

There total 2 articles about Rhenium(O)I(PhCCPh)2 which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 70.0%

: 107060-21-9
ReOI₃(P(C₆H₅)3)2

: 501-65-5
diphenyl acetylene

: 123170-29-6
Rhenium(O)I(PhCCPh)2

Guidance literature:: With water; In dichloromethane; benzene; (N2); stirred for 72 h; stripped to dryness, EtOAc/hexanes (3:2) added, filtered, washed (EtOAc/hexane), filtrate concd., chromd. (silica gel, hexane and EtOAc/hexanes (1:4)), solvent removed in vacuo; elem. anal.;

Reference yield:

: 90623-36-2
Re(O)I₃{As(C₆H₅)3}2

: 501-65-5
diphenyl acetylene

: 123170-29-6
Rhenium(O)I(PhCCPh)2

Guidance literature:: In not given; complex was formed in low yield but was difficult to sep. from the freeacetylene; mass spectral data;
DOI:10.1021/ja00311a039

Reference yield: 97.0%

: 123170-29-6
Rhenium(O)I(PhCCPh)2

: 123170-32-1
NaRe(O)(PhCCPh)2

Guidance literature:: With Na; In tetrahydrofuran; byproducts: NaI; addn. of freshly cut Na metal to Re-compd. and THF at -78°C, stirring for 3 h at -78°C, soln. becomes dark redpurple in colour; filtn. to remove Na, removal of solvent in vacuo, addn. of Et2O, stirring at ambient temp. for 12 h, filtn. to remove NaI, removal of solvent yields viscous oil, elem. anal.;