[(6-hydroxy-9,10-dihydro-11,12-dicarbomethoxyetheno)anthracene-2-yl] 5-[bis(4'-tert-butylbiphenyl-4-yl)amino]-2-nitrobenzoate

Base Information

Chemical Name:[(6-hydroxy-9,10-dihydro-11,12-dicarbomethoxyetheno)anthracene-2-yl] 5-[bis(4'-tert-butylbiphenyl-4-yl)amino]-2-nitrobenzoate
CAS No.:1206196-47-5
Molecular Formula:C₅₉H₅₂N₂O₉
Molecular Weight:933.07
Hs Code.:

Synonyms:[(6-hydroxy-9,10-dihydro-11,12-dicarbomethoxyetheno)anthracene-2-yl] 5-[bis(4'-tert-butylbiphenyl-4-yl)amino]-2-nitrobenzoate

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Chemical Property of [(6-hydroxy-9,10-dihydro-11,12-dicarbomethoxyetheno)anthracene-2-yl] 5-[bis(4'-tert-butylbiphenyl-4-yl)amino]-2-nitrobenzoate

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Technology Process of [(6-hydroxy-9,10-dihydro-11,12-dicarbomethoxyetheno)anthracene-2-yl] 5-[bis(4'-tert-butylbiphenyl-4-yl)amino]-2-nitrobenzoate

There total 5 articles about [(6-hydroxy-9,10-dihydro-11,12-dicarbomethoxyetheno)anthracene-2-yl] 5-[bis(4'-tert-butylbiphenyl-4-yl)amino]-2-nitrobenzoate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 65.0%

: 1206196-46-4
5-[bis(4'-tert-butylbiphenyl-4-yl)amino]-2-nitrobenzoic acid

: 2,6-dihydroxy-9,10-dihydro-11,12-dicarbomethoxyethenoanthracene

: 1206196-47-5
[(6-hydroxy-9,10-dihydro-11,12-dicarbomethoxyetheno)anthracene-2-yl] 5-[bis(4'-tert-butylbiphenyl-4-yl)amino]-2-nitrobenzoate

Guidance literature:: With 4-(dimethylamino)pyridinium tosylate; diisopropyl-carbodiimide; In dichloromethane; at 20 ℃;
DOI:10.1039/b916454e

Reference yield:

: 6950-43-2
5-bromo-2-nitrobenzoic acid

: 1206196-47-5
[(6-hydroxy-9,10-dihydro-11,12-dicarbomethoxyetheno)anthracene-2-yl] 5-[bis(4'-tert-butylbiphenyl-4-yl)amino]-2-nitrobenzoate

Guidance literature:: Multi-step reaction with 4 steps

1: pyridine; thionyl chloride / 4 h / 0 °C / Inert atmosphere

2: 1,1'-bis-(diphenylphosphino)ferrocene; palladium diacetate; caesium carbonate / toluene / 20 h / 80 °C / Inert atmosphere

3: water; sodium hydroxide / 2-ethoxy-ethanol / 0.5 h / Reflux

4: 4-(dimethylamino)pyridinium tosylate; diisopropyl-carbodiimide / dichloromethane / 20 h / 20 °C / Inert atmosphere

With pyridine; 1,1'-bis-(diphenylphosphino)ferrocene; thionyl chloride; water; palladium diacetate; caesium carbonate; 4-(dimethylamino)pyridinium tosylate; sodium hydroxide; diisopropyl-carbodiimide; In 2-ethoxy-ethanol; dichloromethane; toluene; 2: Hartwig-Buchwald cross coupling;
DOI:10.1002/chem.201103411

Reference yield:

: 1078705-10-8
bis(4'-tert-butylbiphenyl-4-yl)amine

: 1206196-47-5
[(6-hydroxy-9,10-dihydro-11,12-dicarbomethoxyetheno)anthracene-2-yl] 5-[bis(4'-tert-butylbiphenyl-4-yl)amino]-2-nitrobenzoate

Guidance literature:: Multi-step reaction with 3 steps

1: 1,1'-bis-(diphenylphosphino)ferrocene; palladium diacetate; caesium carbonate / toluene / 20 h / 80 °C / Inert atmosphere

2: water; sodium hydroxide / 2-ethoxy-ethanol / 0.5 h / Reflux

3: 4-(dimethylamino)pyridinium tosylate; diisopropyl-carbodiimide / dichloromethane / 20 h / 20 °C / Inert atmosphere

With 1,1'-bis-(diphenylphosphino)ferrocene; water; palladium diacetate; caesium carbonate; 4-(dimethylamino)pyridinium tosylate; sodium hydroxide; diisopropyl-carbodiimide; In 2-ethoxy-ethanol; dichloromethane; toluene; 1: Hartwig-Buchwald cross coupling;
DOI:10.1002/chem.201103411