Tris[3-(perfluorooctyl)phenyl]phosphine

Base Information

Chemical Name:Tris[3-(perfluorooctyl)phenyl]phosphine
CAS No.:325459-91-4
Molecular Formula:C₄₂H₁₂F₅₁P
Molecular Weight:1516.45
Hs Code.:
DSSTox Substance ID:DTXSID30412359
Nikkaji Number:J1.455.428I
Wikidata:Q82219680
Mol file:325459-91-4.mol

Synonyms:Tris[3-(perfluorooctyl)phenyl]phosphine;325459-91-4;Tris[3-(1,1,2,2,3,3,4,4,5,5,6,6,7,7,8,8,8-heptadecafluorooctyl)phenyl]phosphane;Tris(3-(perfluorooctyl)phenyl)phosphine;Tris[3-(heptadecafluorooctyl)phenyl]phosphine;DTXSID30412359;VQWYSTZTOSMTTA-UHFFFAOYSA-N;NS00109869

Suppliers and Price of Tris[3-(perfluorooctyl)phenyl]phosphine

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

American Custom Chemicals Corporation
TRIS[3-(HEPTADECAFLUOROOCTYL)PHENYL]PHOSPHINE 95.00%
5MG
$ 500.81

Total 6 raw suppliers

Chemical Property of Tris[3-(perfluorooctyl)phenyl]phosphine

Chemical Property:

Melting Point:88-93 °C
Boiling Point:583.5±50.0 °C(Predicted)
PSA：13.59000
LogP:19.84250
XLogP3:21.4
Hydrogen Bond Donor Count:0
Hydrogen Bond Acceptor Count:51
Rotatable Bond Count:24
Exact Mass:1515.9862236
Heavy Atom Count:94
Complexity:2350

Purity/Quality:

99% ^*data from raw suppliers

TRIS[3-(HEPTADECAFLUOROOCTYL)PHENYL]PHOSPHINE 95.00% ^*data from reagent suppliers

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:

SDS file from LookChem

Total 1 MSDS from other Authors

Useful:

Canonical SMILES:C1=CC(=CC(=C1)P(C2=CC=CC(=C2)C(C(C(C(C(C(C(C(F)(F)F)(F)F)(F)F)(F)F)(F)F)(F)F)(F)F)(F)F)C3=CC=CC(=C3)C(C(C(C(C(C(C(C(F)(F)F)(F)F)(F)F)(F)F)(F)F)(F)F)(F)F)(F)F)C(C(C(C(C(C(C(C(F)(F)F)(F)F)(F)F)(F)F)(F)F)(F)F)(F)F)(F)F

Technology Process of Tris[3-(perfluorooctyl)phenyl]phosphine

There total 4 articles about Tris[3-(perfluorooctyl)phenyl]phosphine which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 59.0%

: 325459-90-3
1-Bromo-3-(1,1,2,2,3,3,4,4,5,5,6,6,7,7,8,8,8-heptadecafluorooctyl)benzene

: 325459-91-4
(C₆H₄(C₈F₁₇))3P

Guidance literature:: 1-Bromo-3-(1,1,2,2,3,3,4,4,5,5,6,6,7,7,8,8,8-heptadecafluorooctyl)benzene; With n-butyllithium; In diethyl ether; hexane; at -78 ℃; for 2h;

With phosphorus trichloride; In diethyl ether; hexane; at -78 - 20 ℃;

Reference yield:

: 507-63-1
1-iodoheptadecafluorooctane

: 325459-91-4
(C₆H₄(C₈F₁₇))3P

Guidance literature:: Multi-step reaction with 3 steps

1.1: Cu / dimethylformamide / 120 °C

2.1: tBuONO; CuBr₂ / acetonitrile / -5 - 20 °C

3.1: nBuLi / diethyl ether; hexane / 2 h / -78 °C

3.2: 59 percent / PCl₃ / diethyl ether; hexane / -78 - 20 °C

With n-butyllithium; tert.-butylnitrite; copper; copper(ll) bromide; In diethyl ether; hexane; N,N-dimethyl-formamide; acetonitrile;

Reference yield:

: 119489-67-7
3-(n-perfluorooctyl)aniline

: 325459-91-4
(C₆H₄(C₈F₁₇))3P

Guidance literature:: Multi-step reaction with 2 steps

1.1: tBuONO; CuBr₂ / acetonitrile / -5 - 20 °C

2.1: nBuLi / diethyl ether; hexane / 2 h / -78 °C

2.2: 59 percent / PCl₃ / diethyl ether; hexane / -78 - 20 °C

With n-butyllithium; tert.-butylnitrite; copper(ll) bromide; In diethyl ether; hexane; acetonitrile;