C₄₁H₆₉Cl₃O₉Si₂

Base Information

Chemical Name:C₄₁H₆₉Cl₃O₉Si₂
CAS No.:160691-42-9
Molecular Formula:C₄₁H₆₉Cl₃O₉Si₂
Molecular Weight:868.523
Hs Code.:

C<sub>41</sub>H<sub>69</sub>Cl<sub>3</sub>O<sub>9</sub>Si<sub>2</sub>

Synonyms:C₄₁H₆₉Cl₃O₉Si₂

Suppliers and Price of C₄₁H₆₉Cl₃O₉Si₂

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 0 raw suppliers

Chemical Property of C₄₁H₆₉Cl₃O₉Si₂

Chemical Property:

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:

Useful:

Technology Process of C₄₁H₆₉Cl₃O₉Si₂

There total 23 articles about C₄₁H₆₉Cl₃O₉Si₂ which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 86534-98-7
(SRS,2S,3R,4S,5R,6R)-3,5-(isopropylidenedioxy)-2,4,6-trimethyl-7-(phenylsulfinyl)heptan-1-ol

: 160691-42-9
C₄₁H₆₉Cl₃O₉Si₂

Guidance literature:: Multi-step reaction with 2 steps

1: 1.) LDA*THF, 3.) W-2 Raney Ni, 4.) (COCl)2, DMSO, 5.) Et₃N, 6.) KMnO₄, pH 7 buffer, 7.) H₂ / 7.) 10percent Pd/C

2: Et₃N / tetrahydrofuran / 2 h

With potassium permanganate; oxalyl dichloride; pH 7 buffer; W-2 Raney Ni; hydrogen; dimethyl sulfoxide; triethylamine; lithium diisopropyl amide; palladium on activated charcoal; In tetrahydrofuran;
DOI:10.1021/ja00104a010

Reference yield:

: 86534-97-6
(2S,3S,4S,5R,6S)-7-hydroxy-3,5-(isopropylidenedioxy)-2,4,6-trimethylheptyl p-toluenesulfonate

: 160691-42-9
C₄₁H₆₉Cl₃O₉Si₂

Guidance literature:: Multi-step reaction with 4 steps

1: 100 percent / tetrahydrofuran / 3 h / Heating

2: 100 percent / NaIO₄ / methanol; H₂O / 21 h / 20 °C

3: 1.) LDA*THF, 3.) W-2 Raney Ni, 4.) (COCl)2, DMSO, 5.) Et₃N, 6.) KMnO₄, pH 7 buffer, 7.) H₂ / 7.) 10percent Pd/C

4: Et₃N / tetrahydrofuran / 2 h

With potassium permanganate; sodium periodate; oxalyl dichloride; pH 7 buffer; W-2 Raney Ni; hydrogen; dimethyl sulfoxide; triethylamine; lithium diisopropyl amide; palladium on activated charcoal; In tetrahydrofuran; methanol; water;
DOI:10.1021/ja00104a010

Reference yield:

: 116661-41-7
(2S,4R,5R)-1-(benzyloxy)-5-hydroxy-2,4,6-trimethylhept-6-en-3-one

: 160691-42-9
C₄₁H₆₉Cl₃O₉Si₂

Guidance literature:: Multi-step reaction with 8 steps

1: 1.) (+)-(Ipc)2BOH, 2.) m-CPBA / 1.) Et₂O, RT, 2 h, 2.) Et₂O, RT, 1 h

2: 95 percent / Et₃N, DMAP / CH₂Cl₂ / 1.5 h / 20 °C

3: 92 percent / PPTS / CH₂Cl₂ / 15 h / 20 °C

4: 92 percent / H₂ / 10percent Pd/C / diisopropyl ether / 2 h / 20 °C

5: 100 percent / tetrahydrofuran / 3 h / Heating

6: 100 percent / NaIO₄ / methanol; H₂O / 21 h / 20 °C

7: 1.) LDA*THF, 3.) W-2 Raney Ni, 4.) (COCl)2, DMSO, 5.) Et₃N, 6.) KMnO₄, pH 7 buffer, 7.) H₂ / 7.) 10percent Pd/C

8: Et₃N / tetrahydrofuran / 2 h

With dmap; potassium permanganate; sodium periodate; oxalyl dichloride; B-hydroxydiisopinocampheylborane; pH 7 buffer; W-2 Raney Ni; hydrogen; pyridinium p-toluenesulfonate; dimethyl sulfoxide; triethylamine; 3-chloro-benzenecarboperoxoic acid; lithium diisopropyl amide; palladium on activated charcoal; In tetrahydrofuran; methanol; dichloromethane; di-isopropyl ether; water;
DOI:10.1021/ja00104a010