Tris[4-(3,3,4,4,5,5,5-heptafluoro-2,2-bis(trifluoromethyl)pentyl)phenyl] phosphine

Base Information

Chemical Name:Tris[4-(3,3,4,4,5,5,5-heptafluoro-2,2-bis(trifluoromethyl)pentyl)phenyl] phosphine
CAS No.:322647-82-5
Molecular Formula:C₃₉H₁₈F₃₉P
Molecular Weight:1258.48
Hs Code.:
DSSTox Substance ID:DTXSID60896148
Nikkaji Number:J1.481.525B
Wikidata:Q82872399
Mol file:322647-82-5.mol

Synonyms:322647-82-5;Tris[4-(3,3,4,4,5,5,5-heptafluoro-2,2-bis(trifluoromethyl)pentyl)phenyl] phosphine;Tris[4-[3,3,4,4,5,5,5-heptafluoro-2,2-bis(trifluoromethyl)pentyl]phenyl]phosphane;TRIS[4-(3 3 4 4 5 5 5-HEPTAFLUORO-2 2-BI;Tris{4-[3,3,4,4,5,5,5-heptafluoro-2,2-bis(trifluoromethyl)pentyl]phenyl}phosphane;Tris(4-(3,3,4,4,5,5,5-heptafluoro-2,2-bis(trifluoromethyl)pentyl)phenyl)phosphine;Tris[4-(3,3,4,4,5,5,5-heptafluoro-2,2-bis(trifluoromethyl)pentyl)phenyl]phosphine;SCHEMBL6763406;DTXSID60896148;ZHQHSVFPOKMCMF-UHFFFAOYSA-N;J-018690;Tris[4-[2,2-bis(trifluoromethyl)-3,3,4,4,5,5,5-heptafluoropentyl]phenyl]phosphine

Suppliers and Price of Tris[4-(3,3,4,4,5,5,5-heptafluoro-2,2-bis(trifluoromethyl)pentyl)phenyl] phosphine

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

American Custom Chemicals Corporation
TRIS[4-(3,3,4,4,5,5,5-HEPTAFLUORO-2,2-BIS(TRIFLUOROMETHYL)PENTYL)PHENYL] PHOSPHINE 95.00%
1G
$ 978.69

Total 6 raw suppliers

Chemical Property of Tris[4-(3,3,4,4,5,5,5-heptafluoro-2,2-bis(trifluoromethyl)pentyl)phenyl] phosphine

Chemical Property:

Vapor Pressure:0mmHg at 25°C
Boiling Point:519.302°C at 760 mmHg
Flash Point:267.864°C
PSA：13.59000
LogP:16.90400
XLogP3:19.8
Hydrogen Bond Donor Count:0
Hydrogen Bond Acceptor Count:39
Rotatable Bond Count:15
Exact Mass:1258.0523359
Heavy Atom Count:79
Complexity:1740

Purity/Quality:

98%Min ^*data from raw suppliers

TRIS[4-(3,3,4,4,5,5,5-HEPTAFLUORO-2,2-BIS(TRIFLUOROMETHYL)PENTYL)PHENYL] PHOSPHINE 95.00% ^*data from reagent suppliers

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:

SDS file from LookChem

Total 1 MSDS from other Authors

Useful:

Canonical SMILES:C1=CC(=CC=C1CC(C(C(C(F)(F)F)(F)F)(F)F)(C(F)(F)F)C(F)(F)F)P(C2=CC=C(C=C2)CC(C(C(C(F)(F)F)(F)F)(F)F)(C(F)(F)F)C(F)(F)F)C3=CC=C(C=C3)CC(C(C(C(F)(F)F)(F)F)(F)F)(C(F)(F)F)C(F)(F)F

Technology Process of Tris[4-(3,3,4,4,5,5,5-heptafluoro-2,2-bis(trifluoromethyl)pentyl)phenyl] phosphine

There total 4 articles about Tris[4-(3,3,4,4,5,5,5-heptafluoro-2,2-bis(trifluoromethyl)pentyl)phenyl] phosphine which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 49.0%

: 149068-60-0
4-[3,3,4,4,5,5,5-heptafluoro-2,2-bis(trifluoromethyl)pentyl]-1-bromobenzene

: 322647-82-5
tris[4-(3,3,4,4,5,5,5-heptafluoro-2,2-bis(trifluoromethyl)pentyl)phenyl]phosphane

: tris[4-(3,3,4,4,5,5,5-heptafluoro-2,2-bis(trifluoromethyl)pentyl)phenyl]phosphine oxide

Guidance literature:: 4-[3,3,4,4,5,5,5-heptafluoro-2,2-bis(trifluoromethyl)pentyl]-1-bromobenzene; With tert.-butyl lithium; In diethyl ether; pentane; at -78 ℃;

With phosphorus trichloride; In diethyl ether; pentane; at -78 - 20 ℃;
DOI:10.1021/jo000464f

Reference yield:

: 1584-03-8
perfluoro-2-methylpent-2-ene

: 322647-82-5
tris[4-(3,3,4,4,5,5,5-heptafluoro-2,2-bis(trifluoromethyl)pentyl)phenyl]phosphane

Guidance literature:: Multi-step reaction with 2 steps

1.1: cesium fluoride / dimethylformamide / 36 h / 45 °C

1.2: 89 percent / dimethylformamide / 14 h / 65 °C

2.1: t-BuLi / diethyl ether; pentane / -78 °C

2.2: 49 percent / phosphorus trichloride / diethyl ether; pentane / -78 - 20 °C

With tert.-butyl lithium; cesium fluoride; In diethyl ether; N,N-dimethyl-formamide; pentane;
DOI:10.1021/jo000464f

Reference yield:

: 55883-45-9
4-bromobenzyliodide

: 322647-82-5
tris[4-(3,3,4,4,5,5,5-heptafluoro-2,2-bis(trifluoromethyl)pentyl)phenyl]phosphane

Guidance literature:: Multi-step reaction with 2 steps

1.1: cesium fluoride / dimethylformamide / 36 h / 45 °C

1.2: 89 percent / dimethylformamide / 14 h / 65 °C

2.1: t-BuLi / diethyl ether; pentane / -78 °C

2.2: 49 percent / phosphorus trichloride / diethyl ether; pentane / -78 - 20 °C

With tert.-butyl lithium; cesium fluoride; In diethyl ether; N,N-dimethyl-formamide; pentane;
DOI:10.1021/jo000464f