octadecahydro-1-benzyl-2-oxo-1,6,7-metheno-1H-cyclopenta<3,4>pentaleno<2,1,6-gha>pentaleno<1,2,3-cd>pentalene

Base Information

• Chemical Name: octadecahydro-1-benzyl-2-oxo-1,6,7-metheno-1H-cyclopenta<3,4>pentaleno<2,1,6-gha>pentaleno<1,2,3-cd>pentalene
• CAS No.: 107201-26-3
• Molecular Formula: C₂₇H₂₈O
• Molecular Weight: 368.519
• Mol file: 107201-26-3.mol

Synonyms:octadecahydro-1-benzyl-2-oxo-1,6,7-metheno-1H-cyclopenta<3,4>pentaleno<2,1,6-gha>pentaleno<1,2,3-cd>pentalene

Chemical Property of octadecahydro-1-benzyl-2-oxo-1,6,7-metheno-1H-cyclopenta<3,4>pentaleno<2,1,6-gha>pentaleno<1,2,3-cd>pentalene

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of octadecahydro-1-benzyl-2-oxo-1,6,7-metheno-1H-cyclopenta<3,4>pentaleno<2,1,6-gha>pentaleno<1,2,3-cd>pentalene

There total 1 articles about octadecahydro-1-benzyl-2-oxo-1,6,7-metheno-1H-cyclopenta<3,4>pentaleno<2,1,6-gha>pentaleno<1,2,3-cd>pentalene which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 66.0%

octadecahydro-7-benzyl-1,6,7-metheno-1H-cyclopenta<3,4>pentaleno<2,1,6-gha>pentaleno<1,2,3-cd>pentalen-2-ol (107201-25-2,107297-03-0) → octadecahydro-1-benzyl-2-oxo-1,6,7-metheno-1H-cyclopenta<3,4>pentaleno<2,1,6-gha>pentaleno<1,2,3-cd>pentalene (107201-26-3)

Guidance literature:

With pyridinium chlorochromate; In dichloromethane; for 4h; Ambient temperature;

DOI:10.1021/jo00383a017

Reference yield:

octadecahydro-1-benzyl-2-oxo-1,6,7-metheno-1H-cyclopenta<3,4>pentaleno<2,1,6-gha>pentaleno<1,2,3-cd>pentalene (107201-26-3) → hexadecahydro-7-benzyl-1,6,2,5-ethanediylidenecyclopenta<3,4>pentaleno<2,1,6-cde>pentaleno<2,1,6-gha>pentalen-3b(1H)-ol (107201-27-4)

Guidance literature:

In tert-butyl alcohol; benzene; for 5.5h; Irradiation;

DOI:10.1021/jo00383a017

upstream raw materials:

octadecahydro-7-benzyl-1,6,7-metheno-1H-cyclopenta<3,4>pentaleno<2,1,6-gha>pentaleno<1,2,3-cd>pentalen-2-ol

Downstream raw materials:

hexadecahydro-7-benzyl-1,6,2,5-ethanediylidenecyclopenta<3,4>pentaleno<2,1,6-cde>pentaleno<2,1,6-gha>pentalen-3b(1H)-ol