(Z)-2-(dimethylphenylsilyl)-1-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)-6,8,11-trioxa-1-dodecene

Base Information

• Chemical Name: (Z)-2-(dimethylphenylsilyl)-1-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)-6,8,11-trioxa-1-dodecene
• CAS No.: 185989-95-1
• Molecular Formula: C₂₃H₃₉BO₅Si
• Molecular Weight: 434.456
• Mol file: 185989-95-1.mol

Synonyms:(Z)-2-(dimethylphenylsilyl)-1-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)-6,8,11-trioxa-1-dodecene

Chemical Property of (Z)-2-(dimethylphenylsilyl)-1-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)-6,8,11-trioxa-1-dodecene

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of (Z)-2-(dimethylphenylsilyl)-1-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)-6,8,11-trioxa-1-dodecene

There total 3 articles about (Z)-2-(dimethylphenylsilyl)-1-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)-6,8,11-trioxa-1-dodecene which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 85.0%

5-((2-methoxyethoxy)methoxy)pent-1-yne (98076-86-9) + dimethylphenyl(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)silane (185990-03-8) → (Z)-2-(dimethylphenylsilyl)-1-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)-6,8,11-trioxa-1-dodecene (185989-95-1)

Guidance literature:

1,1,3,3-tetramethylbutane isonitrile; palladium diacetate; In toluene; Heating;

DOI:10.1016/S0040-4020(99)00444-5

Reference yield:

2,3-dimethyl-2,3-butane diol (76-09-5) → (Z)-2-(dimethylphenylsilyl)-1-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)-6,8,11-trioxa-1-dodecene (185989-95-1)

Guidance literature:

Multi-step reaction with 2 steps

1: 79 percent / CH₂Cl₂ / 10 h / 20 °C

2: 85 percent / palladium(II) acetate; 1,1,3,3-tetramethylbutyl isocyanide / toluene / Heating

1,1,3,3-tetramethylbutane isonitrile; palladium diacetate; In dichloromethane; toluene; 1: Substitution / 2: Addition;

DOI:10.1016/S0040-4020(99)00444-5

Reference yield:

(bis(diethylamino)-boranyl)dimethylphenylsilane (166329-94-8) → (Z)-2-(dimethylphenylsilyl)-1-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)-6,8,11-trioxa-1-dodecene (185989-95-1)

Guidance literature:

Multi-step reaction with 2 steps

1: 79 percent / CH₂Cl₂ / 10 h / 20 °C

2: 85 percent / palladium(II) acetate; 1,1,3,3-tetramethylbutyl isocyanide / toluene / Heating

1,1,3,3-tetramethylbutane isonitrile; palladium diacetate; In dichloromethane; toluene; 1: Substitution / 2: Addition;

DOI:10.1016/S0040-4020(99)00444-5

upstream raw materials:

5-((2-methoxyethoxy)methoxy)pent-1-yne

dimethylphenyl(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)silane

2,3-dimethyl-2,3-butane diol

(bis(diethylamino)-boranyl)dimethylphenylsilane