3-[1-(benzyloxy)methyl-2,5-dihydro-2,5-dioxopyrrol-3-yl]-1-(1-deoxy-2,3,4,6-tetra-O-benzyl-β-D-glucopyranos-1-yl)-1H-indole

Base Information

Chemical Name:3-[1-(benzyloxy)methyl-2,5-dihydro-2,5-dioxopyrrol-3-yl]-1-(1-deoxy-2,3,4,6-tetra-O-benzyl-β-D-glucopyranos-1-yl)-1H-indole
CAS No.:877610-64-5
Molecular Formula:C₅₄H₅₀N₂O₈
Molecular Weight:855
Hs Code.:

Synonyms:3-[1-(benzyloxy)methyl-2,5-dihydro-2,5-dioxopyrrol-3-yl]-1-(1-deoxy-2,3,4,6-tetra-O-benzyl-β-D-glucopyranos-1-yl)-1H-indole

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Chemical Property of 3-[1-(benzyloxy)methyl-2,5-dihydro-2,5-dioxopyrrol-3-yl]-1-(1-deoxy-2,3,4,6-tetra-O-benzyl-β-D-glucopyranos-1-yl)-1H-indole

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Technology Process of 3-[1-(benzyloxy)methyl-2,5-dihydro-2,5-dioxopyrrol-3-yl]-1-(1-deoxy-2,3,4,6-tetra-O-benzyl-β-D-glucopyranos-1-yl)-1H-indole

There total 5 articles about 3-[1-(benzyloxy)methyl-2,5-dihydro-2,5-dioxopyrrol-3-yl]-1-(1-deoxy-2,3,4,6-tetra-O-benzyl-β-D-glucopyranos-1-yl)-1H-indole which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 91.0%

: 877610-62-3
3-[1-(benzyloxy)methyl-2,5-dioxopyrrolidin-3-yl]-1-(1-deoxy-2,3,4,6-tetra-O-benzyl-β-D-glucopyranos-1-yl)-indole

: 877610-64-5
3-[1-(benzyloxy)methyl-2,5-dihydro-2,5-dioxopyrrol-3-yl]-1-(1-deoxy-2,3,4,6-tetra-O-benzyl-β-D-glucopyranos-1-yl)-1H-indole

Guidance literature:: With 2,3-dicyano-5,6-dichloro-p-benzoquinone; In 1,4-dioxane; at 20 ℃; for 3h;
DOI:10.1016/j.tet.2005.10.077

Reference yield:

: 877610-60-1
3-[1-(benzyloxy)methyl-3-bromo-2,5-dihydro-2,5-dioxopyrrol-4-yl]-1-(1-deoxy-2,3,4,6-tetra-O-benzyl-β-D-glucopyranos-1-yl)-indole

: 877610-64-5
3-[1-(benzyloxy)methyl-2,5-dihydro-2,5-dioxopyrrol-3-yl]-1-(1-deoxy-2,3,4,6-tetra-O-benzyl-β-D-glucopyranos-1-yl)-1H-indole

: 877610-62-3
3-[1-(benzyloxy)methyl-2,5-dioxopyrrolidin-3-yl]-1-(1-deoxy-2,3,4,6-tetra-O-benzyl-β-D-glucopyranos-1-yl)-indole

Guidance literature:: With pyridine; hydrogen; palladium on activated charcoal; In tetrahydrofuran; methanol; for 8h; under 760 Torr;
DOI:10.1016/j.tet.2005.10.077

Reference yield:

: 4291-69-4,6386-24-9,6564-72-3,59531-24-7,69257-52-9,78184-89-1,78609-16-2,78609-17-3,78609-18-4,96553-53-6,104111-61-7,131347-08-5,4132-28-9
2,3,4,6-Tetra-O-benzyl-D-glucopyranose

: 877610-64-5
3-[1-(benzyloxy)methyl-2,5-dihydro-2,5-dioxopyrrol-3-yl]-1-(1-deoxy-2,3,4,6-tetra-O-benzyl-β-D-glucopyranos-1-yl)-1H-indole

Guidance literature:: Multi-step reaction with 2 steps

1: 92 percent / triphenylphosphine; DIAD / tetrahydrofuran / -78 - 20 °C

2: H₂; pyridine / Pd/C / methanol; tetrahydrofuran / 8 h / 760 Torr

With pyridine; di-isopropyl azodicarboxylate; hydrogen; triphenylphosphine; palladium on activated charcoal; In tetrahydrofuran; methanol; 1: Mitsunobu reaction;
DOI:10.1016/j.tet.2005.10.077