2-(3',4'-dimethoxycinnamyl)-2-methylcyclopentane-1,3-dione

Base Information

• Chemical Name: 2-(3',4'-dimethoxycinnamyl)-2-methylcyclopentane-1,3-dione
• CAS No.: 160514-96-5
• Molecular Formula: C₁₇H₂₀O₄
• Molecular Weight: 288.343
• Mol file: 160514-96-5.mol

Synonyms:2-(3',4'-dimethoxycinnamyl)-2-methylcyclopentane-1,3-dione

Chemical Property of 2-(3',4'-dimethoxycinnamyl)-2-methylcyclopentane-1,3-dione

Chemical Property:

Purity/Quality:

Safty Information:

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MSDS Files:

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Technology Process of 2-(3',4'-dimethoxycinnamyl)-2-methylcyclopentane-1,3-dione

There total 1 articles about 2-(3',4'-dimethoxycinnamyl)-2-methylcyclopentane-1,3-dione which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 98.6%

2-Methylcyclopentane-1,3-dione (765-69-5) + 1'-Hydroxymethyleugenol (31706-95-3) → 2-(3',4'-dimethoxycinnamyl)-2-methylcyclopentane-1,3-dione (160514-96-5)

Guidance literature:

With tetrakis(triphenylphosphine) palladium⁽⁰⁾; In tetrahydrofuran; for 0.5h; Product distribution; Heating; further solvents and catalysts;

DOI:10.1016/0040-4039(94)80036-7

Reference yield: 60.3%

2-(3',4'-dimethoxycinnamyl)-2-methylcyclopentane-1,3-dione (160514-96-5) → (2R,3S)-2-[(E)-3-(3,4-Dimethoxy-phenyl)-allyl]-3-hydroxy-2-methyl-cyclopentanone (170715-58-9)

Guidance literature:

With triton X₁₀₀; Sucrose; In ethanol; at 27 ℃; for 19h; bakers' yeast;

DOI:10.1271/bbb.59.1300

Reference yield: 25.8%

2-(3',4'-dimethoxycinnamyl)-2-methylcyclopentane-1,3-dione (160514-96-5) → (2S,3S)-2-[(E)-3-(3,4-Dimethoxy-phenyl)-allyl]-3-hydroxy-2-methyl-cyclopentanone (170503-95-4)

Guidance literature:

With triton X₁₀₀; Sucrose; In ethanol; at 27 ℃; for 192h; pre-cultivated culture of KI 0117 strain;

DOI:10.1271/bbb.59.1300

upstream raw materials:

2-Methylcyclopentane-1,3-dione

1'-Hydroxymethyleugenol

Downstream raw materials:

(2R,3S)-2-[(E)-3-(3,4-Dimethoxy-phenyl)-allyl]-3-hydroxy-2-methyl-cyclopentanone

(2S,3S)-2-[(E)-3-(3,4-Dimethoxy-phenyl)-allyl]-3-hydroxy-2-methyl-cyclopentanone