Technology Process of C29H46O7
There total 6 articles about C29H46O7 which
guide to synthetic route it.
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synthetic route:
- Guidance literature:
-
With
tetrabutyl ammonium fluoride;
In
tetrahydrofuran;
at 20 ℃;
for 3h;
DOI:10.1021/ol4017518
- Guidance literature:
-
Multi-step reaction with 2 steps
1.1: 9-methoxy-9-BBN; tert.-butyl lithium / tetrahydrofuran; hexane; diethyl ether; pentane / 4 h / -78 - 20 °C
1.2: 0.33 h / 20 °C
1.3: 13 h / 50 °C
2.1: tetrabutyl ammonium fluoride / tetrahydrofuran / 3 h / 20 °C
With
tetrabutyl ammonium fluoride; tert.-butyl lithium; 9-methoxy-9-BBN;
In
tetrahydrofuran; diethyl ether; hexane; pentane;
DOI:10.1021/ol4017518
- Guidance literature:
-
Multi-step reaction with 7 steps
1.1: hydroquinidein 1,4-phthalazinediyl diether; potassium hexacyanoferrate(III); osmium(VIII) oxide; methanesulfonamide; potassium carbonate / water; tert-butyl alcohol / 23 h / 0 °C
2.1: 2,6-dimethylpyridine / dichloromethane / 0 - 20 °C
3.1: 2,3-dicyano-5,6-dichloro-p-benzoquinone / dichloromethane / 1.17 h / 20 °C / pH 7
4.1: triethylamine; dmap / dichloromethane / 25 h / 0 - 20 °C
5.1: sodium iodide / acetone / 18 h / 50 °C
6.1: 9-methoxy-9-BBN; tert.-butyl lithium / tetrahydrofuran; hexane; diethyl ether; pentane / 4 h / -78 - 20 °C
6.2: 0.33 h / 20 °C
6.3: 13 h / 50 °C
7.1: tetrabutyl ammonium fluoride / tetrahydrofuran / 3 h / 20 °C
With
2,6-dimethylpyridine; dmap; osmium(VIII) oxide; methanesulfonamide; tetrabutyl ammonium fluoride; tert.-butyl lithium; potassium carbonate; hydroquinidein 1,4-phthalazinediyl diether; triethylamine; 9-methoxy-9-BBN; 2,3-dicyano-5,6-dichloro-p-benzoquinone; sodium iodide; potassium hexacyanoferrate(III);
In
tetrahydrofuran; diethyl ether; hexane; dichloromethane; water; acetone; tert-butyl alcohol; pentane;
1.1: |Sharpless Dihydroxylation;
DOI:10.1021/ol4017518
