Acetic acid 1-[1-((1R,2S,6R)-2,6-bis-benzyloxy-cyclohexyloxy)-meth-(Z)-ylidene]-2-(tert-butyl-dimethyl-silanyloxy)-allyl ester

Base Information

Chemical Name:Acetic acid 1-[1-((1R,2S,6R)-2,6-bis-benzyloxy-cyclohexyloxy)-meth-(Z)-ylidene]-2-(tert-butyl-dimethyl-silanyloxy)-allyl ester
CAS No.:102922-68-9
Molecular Formula:C₃₂H₄₄O₆Si
Molecular Weight:552.783
Hs Code.:

Synonyms:Acetic acid 1-[1-((1R,2S,6R)-2,6-bis-benzyloxy-cyclohexyloxy)-meth-(Z)-ylidene]-2-(tert-butyl-dimethyl-silanyloxy)-allyl ester

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Chemical Property of Acetic acid 1-[1-((1R,2S,6R)-2,6-bis-benzyloxy-cyclohexyloxy)-meth-(Z)-ylidene]-2-(tert-butyl-dimethyl-silanyloxy)-allyl ester

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Technology Process of Acetic acid 1-[1-((1R,2S,6R)-2,6-bis-benzyloxy-cyclohexyloxy)-meth-(Z)-ylidene]-2-(tert-butyl-dimethyl-silanyloxy)-allyl ester

There total 5 articles about Acetic acid 1-[1-((1R,2S,6R)-2,6-bis-benzyloxy-cyclohexyloxy)-meth-(Z)-ylidene]-2-(tert-butyl-dimethyl-silanyloxy)-allyl ester which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 99.0%

: 69739-34-0
t-butyldimethylsiyl triflate

: 102940-31-8
(Z)-2-acetoxy-1-(<(1α,2β,6β)-2,6-bis(phenylmethoxy)-1-cyclohexyl>oxy)-1-buten-3-one

: 102922-68-9
Acetic acid 1-[1-((1R,2S,6R)-2,6-bis-benzyloxy-cyclohexyloxy)-meth-(Z)-ylidene]-2-(tert-butyl-dimethyl-silanyloxy)-allyl ester

Guidance literature:: With triethylamine; In diethyl ether; at 0 ℃; for 0.166667h;
DOI:10.1021/ja00274a049

Reference yield:

: 74441-37-5
2-acetoxy-1-methoxy-1-buten-3-one

: 102922-68-9
Acetic acid 1-[1-((1R,2S,6R)-2,6-bis-benzyloxy-cyclohexyloxy)-meth-(Z)-ylidene]-2-(tert-butyl-dimethyl-silanyloxy)-allyl ester

Guidance literature:: Multi-step reaction with 2 steps

1: 72 percent / benzene / 20 h / Heating

2: 99 percent / triethylamine / diethyl ether / 0.17 h / 0 °C

With triethylamine; In diethyl ether; benzene;
DOI:10.1021/ja00274a049

Reference yield:

: 32700-48-4
[(cyclohex-2-en-1-yloxy)methyl]benzene

: 102922-68-9
Acetic acid 1-[1-((1R,2S,6R)-2,6-bis-benzyloxy-cyclohexyloxy)-meth-(Z)-ylidene]-2-(tert-butyl-dimethyl-silanyloxy)-allyl ester

Guidance literature:: Multi-step reaction with 4 steps

1: 41 percent / m-chloroperoxybenzoic acid / CH₂Cl₂ / Ambient temperature

2: 65 percent / 60 percent sodium hydride / paraffin; dimethylformamide / 10 h / 100 °C

3: 72 percent / benzene / 20 h / Heating

4: 99 percent / triethylamine / diethyl ether / 0.17 h / 0 °C

With sodium hydride; triethylamine; 3-chloro-benzenecarboperoxoic acid; In diethyl ether; dichloromethane; N,N-dimethyl-formamide; paraffin; benzene;
DOI:10.1021/ja00274a049