Os₃(CO)12(CH₂CO)

Base Information

Chemical Name:Os₃(CO)12(CH₂CO)
CAS No.:85883-28-9
Molecular Formula:C₁₄H₂O₁₃Os₃
Molecular Weight:948.762
Hs Code.:

Synonyms:Os₃(CO)12(CH₂CO)

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Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of Os₃(CO)12(CH₂CO)

Chemical Property:

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Technology Process of Os₃(CO)12(CH₂CO)

There total 2 articles about Os₃(CO)12(CH₂CO) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 39.0%

: Os3(CO)10(μ-CO)(μ-CH2)

: 15696-40-9
dodecacarbonyl triosmium

: 85883-28-9
Os₃(CO)12(CH₂CO)

Guidance literature:: With carbon monoxide; In dichloromethane; byproducts: diketene; stirring of a complex soln. under 1 atm of CO; volatile products were distilled in vac.; residue was redissolved in CH2Cl2, Os3(CO)12 was filtered off; evapn.; recrystn. (CH2Cl2-hexane, -50°C); elem. anal.;
DOI:10.1021/ja00329a023

Reference yield:

: Os3(CO)10(μ-CO)(μ-CH2)

: 15696-40-9
C₁₂O₁₂Os₃

: 85883-28-9
Os₃(CO)12(CH₂CO)

Guidance literature:: With CO; In dichloromethane; Os complex reacting with CO in CH2Cl2 for 2-8 h at 22°C, filtering to remove Os3(CO)12, evapg.; purified by recrystn. from CH2Cl2/cyclohexane at 4°C; identifiedby IR, NMR, mass spectra and single crystal X-ray diffraction;
DOI:10.1021/ja00350a066

Reference yield:

: 85883-28-9
Os₃(CO)12(CH₂CO)

: 109-73-9,85404-21-3
N-butylamine

: 15696-40-9
dodecacarbonyl triosmium

: 1119-49-9
N-butylacetamide

Guidance literature:: With CO; In dichloromethane; free amine was added to a soln. of Os3-cluster under a CO atmosphere; very slow (4 d) reaction occured; IR spectral data;